Cross-Double Deoxygenative Carbon–Carbon Bond Formation between Benzyl Benzoates and Allylic Alcohols

Li, Zhongxian; Wang, Liwei; Zeng, Tianlong; Huang, Zhihui; Song, Shuo; Qi, Xiaotian; Zhu, Jun

doi:10.1021/acscatal.4c01857

ACS Catal.

2024

DOI: 10.1021/acscatal.4c01857

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Cross-Double Deoxygenative Carbon–Carbon Bond Formation between Benzyl Benzoates and Allylic Alcohols

Zhongxian Li,

Liwei Wang,

Tianlong Zeng

et al.

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2024

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Cited by 2 publications

References 80 publications

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Asymmetric radical allylation of β-keto esters with vinyl cyclopropanes by dual photoredox/nickel catalysis

Qu,

Zhou,

Xiao

et al. 2024

Sci. China Chem.

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Asymmetric radical allylation of β-keto esters with vinyl cyclopropanes by dual photoredox/nickel catalysis

Qu,

Zhou,

Xiao

et al. 2024

Sci. China Chem.

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Chemoselective Cleavage and Transamidation of Tertiary p-Methoxybenzyl Amides under Metal-Free Photoredox Catalysis

Jeong,

Lee,

Maruoka

2024

Org. Lett.

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A metal-free and mild cleavage of tertiary p-methoxybenzyl amides (PMB tert-amide) under photoredox conditions is developed using Mes-Acr-Ph + BF 4− and Selectfluor to activate the electron-rich benzylic C−H bond of the PMB moiety. The resulting acyl fluoride intermediate is versatile and facilitates a one-pot transamidation of the PMB tert-amide. The value of this protocol is highlighted by performing the chemoselective activation of the PMB tert-amide in bifunctional molecules containing more reactive functionalities than the amide.

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Cross-Double Deoxygenative Carbon–Carbon Bond Formation between Benzyl Benzoates and Allylic Alcohols

Cited by 2 publications

References 80 publications

Asymmetric radical allylation of β-keto esters with vinyl cyclopropanes by dual photoredox/nickel catalysis

Asymmetric radical allylation of β-keto esters with vinyl cyclopropanes by dual photoredox/nickel catalysis

Chemoselective Cleavage and Transamidation of Tertiary p-Methoxybenzyl Amides under Metal-Free Photoredox Catalysis

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