A quantitative "cross-language assimilation overlap" method for testing predictions of the Perceptual Assimilation Model ͑PAM͒ was implemented to compare results of a discrimination experiment with the listeners' previously reported assimilation data. The experiment examined discrimination of Parisian French ͑PF͒ front rounded vowels /y/ and /oe/. Three groups of American English listeners differing in their French experience ͑no experience ͓NoExp͔, formal experience ͓ModExp͔, and extensive formal-plus-immersion experience ͓HiExp͔͒ performed discrimination of PF /y-u/, /y-o/, /oe-o/, /oe-u/, /y-i/, /y-ε/, /oe-ε/, /oe-i/, /y-oe/, /u-i/, and /a-ε/. Vowels were in bilabial /rabVp/ and alveolar /radVt/ contexts. More errors were found for PF front vs back rounded vowel pairs ͑16%͒ than for PF front unrounded vs rounded pairs ͑2%͒. Overall, ModExp listeners did not perform more accurately ͑11% errors͒ than NoExp listeners ͑13% errors͒. Extensive immersion experience, however, was associated with fewer errors ͑3%͒ than formal experience alone, although discrimination of PF /y-u/ remained relatively poor ͑12% errors͒ for HiExp listeners. More errors occurred on pairs involving front vs back rounded vowels in alveolar context ͑20% errors͒ than in bilabial ͑11% errors͒. Significant correlations were revealed between listeners' assimilation overlap scores and their discrimination errors, suggesting that the PAM may be extended to second-language ͑L2͒ vowel learning.