The pursuit of large-scale quantum computing has captivated the scientific community, and the potential of cryogenic circuits using mature CMOS technologies represents a significant step forward in this quest. Nevertheless, the operation of circuits at cryogenic temperatures poses significant challenges due to the strict power and timing constraints. These challenges are compounded by the well-known Von Neumann bottleneck that plays a major role in limiting the throughput and energy efficiency of modern computing systems. To overcome such a bottleneck, In-Memory Computing (IMC) is rapidly emerging as a promising solution for creating hardware accelerators that go far beyond Von Neumann principles, offering substantial efficiency improvements. In this work, we investigate the effectiveness of cryogenic brain-inspired hyperdimensional IMC using emerging Ferroelectric (FE) technologies at the 5 nm node. To achieve that, we begin by characterizing commercial 5 nm FinFETs from room temperature (300 K) down to cryogenic temperature (10 K). Then, we carefully calibrate the first industry-standard cryogenic-aware compact model (BSIM-CMG) to accurately reproduce the measurements. Afterward, we incorporate a physics-based FE model within the BSIM-CMG model and calibrated it against FE capacitor measurements to realize Fe-FinFET devices operating from 300 K down to 10 K. Then, as proof of concept, we focus on 1×8 Ternary Content Addressable Memory (TCAM) array that we use to perform the language classification using brain-inspired hyperdimensional IMC. Our comprehensive analysis spans from investigating the delay, power, and energy efficiency of IMC-based TCAM all the way up to calculating error probabilities in which we compare the figure of merits obtained from the emerging Fe-FinFET against classical FinFET-based IMC.