2020
DOI: 10.3389/fchem.2020.00494
|View full text |Cite
|
Sign up to set email alerts
|

Cross-Metathesis of Methallyl Halides: Concise Enantioselective Formal Total Synthesis of (–)-Presphaerene

Abstract: The cross-metathesis (CM) of methallyl halides catalyzed using four different ruthenium-based complexes-Grubbs catalyst, Grubbs second-generation catalyst, Hoveyda-Grubbs second-generation catalyst, and Stewart-Grubbs catalyst-was investigated. When methallyl chloride or bromide was reacted with a model substrate containing a benzyl ether group, the Grubbs catalyst, and Grubbs second-generation catalyst did not promote the reaction well. However, the Hoveyda-Grubbs second-generation catalyst and Stewart-Grubbs… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

0
1
0

Year Published

2021
2021
2023
2023

Publication Types

Select...
2

Relationship

0
2

Authors

Journals

citations
Cited by 2 publications
(1 citation statement)
references
References 26 publications
0
1
0
Order By: Relevance
“…We added Grubbs second generation catalyst to initiate the ROMP reaction, which involved the crosslinking of the two structures with the C C double bond of the main chain. 29 The grubbs second generation catalysts are known for their high activity and long lifespan, [30][31][32] and have been widely applied in various fields. DCPD possesses certain properties that make it a suitable crosslinking agent.…”
mentioning
confidence: 99%
“…We added Grubbs second generation catalyst to initiate the ROMP reaction, which involved the crosslinking of the two structures with the C C double bond of the main chain. 29 The grubbs second generation catalysts are known for their high activity and long lifespan, [30][31][32] and have been widely applied in various fields. DCPD possesses certain properties that make it a suitable crosslinking agent.…”
mentioning
confidence: 99%