Background: Multi-center (molecular) structures can play an important role in light nuclei. The highly deformed rotational band in 10 Be with band head at 6.179 MeV has been observed recently and suggested to have an exotic α:2n:α configuration.Purpose: Search for states with α:pn:α two-center molecular configurations in 10 B that are analogous to the states with α:2n:α structure in 10 Be.Method: The T=1 isobaric analog states in 10 B were studied in the energy range of Ex = 8.7 − 12.1 MeV using the reaction 1 H( 9 Be,α) 6 Li*(T=1, 0 + , 3.56 MeV). An R-matrix analysis was used to extract parameters for the states observed in the (p,α) excitation function.Results: Five T=1 states in 10 B have been identified. The known 2 + and 3 − states at 8.9 MeV have been observed and their partial widths have been measured. The spin-parities and partial widths for three higher lying states were determined.Conclusions: Our data support theoretical predictions that the 2 + state at 8.9 MeV (isobaric analog of the 7.54 MeV state in 10 Be) is a highly clustered state and can be identified as a member of the α:np:α rotational band. The next member of this band, the 4 + state, has not been found. A very broad 0 + state at 11 MeV that corresponds to pure α+ 6 Li(0 + ,T=1) configuration is suggested and it might be related to similar structures found in 12 C, 18 O and 20 Ne.