Crosslinking of Sulfonated Cotton Cellulose

Han, Tsung-Yuan; Chen, Cheng‐Chi

doi:10.1177/004051759806800206

Cited by 8 publications

(3 citation statements)

References 18 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…(b) Calculation of Activation Energy. The relationship between reaction rate and temperature is given by the Arrhenius formula [28][29][30], which is expressed as Equation ( 6):…”

Section: Calculation Of Arrhenius Formulamentioning

confidence: 99%

New Method to Evaluate the Crosslinking Degree of Resin Finishing Agent with Cellulose Using Kjeldahl Method and Arrhenius Formula

Lou

Zhang²,

et al. 2021

Processes

View full text Add to dashboard Cite

In anti-wrinkle finishing, the crosslinking degree of fabric is mainly determined by wrinkle recovery angle, stiffness, and viscosity, these indicators can only reflect the finishing effect from a macro perspective, which cannot reflect whether the crosslinking is sufficient, and it is difficult to quantify the crosslinking degree. In this paper, we combined the Kjeldahl method with the Arrhenius formula and proposed a method to analyze the crosslinking degree of dimethyloldihydroxyethyleneurea (two-dimensional (2D) resin) with cotton cellulose during delayed-cure finishing for the first time. The nitrogen content of completed fabrics during storage was measured by the Kjeldahl method, and the reaction rate equation of the 2D resin and cellulose under normal temperature conditions was calculated. The results show that the nitrogen content is more suitable to indicate the crosslinking degree, and the apparent activation energy was 28.271 kJ/mol and the pre-finger factor was 0.622, which indicated that the 2D resin was prone to cross-linking with cotton fabrics during storage. During long-term storage, the relative errors between the calculated and measured values of the nitrogen content were within ±5%, and the accuracy was higher than the traditional evaluation method. The stability of 2D resins during the storage of delayed-curing finishing was also analyzed through this method.

show abstract

“…(b) Calculation of Activation Energy. The relationship between reaction rate and temperature is given by the Arrhenius formula [28][29][30], which is expressed as Equation ( 6):…”

Section: Calculation Of Arrhenius Formulamentioning

confidence: 99%

New Method to Evaluate the Crosslinking Degree of Resin Finishing Agent with Cellulose Using Kjeldahl Method and Arrhenius Formula

Lou

Zhang²,

et al. 2021

Processes

View full text Add to dashboard Cite

show abstract

“…Cotton fiber can be degraded in nature environment, cotton has large amount of hydrophilic group, during degradation with aging, water and water vapor will accelerate the process and some hydrolysis reaction, molecular weight decreases. Cellulose macromolecule fractures by the reaction of microorganism, and the construction of the whole subject will be destroyed [7]. The sample with chitosan can also be degraded completely as the biodegradability of chitosan.…”

Section: Degradation Propertymentioning

confidence: 99%

Preparation and Analysis of Cotton Nonwoven Film Strengthened by Chitosan

Jia

Hong

Pei

et al. 2011

AMR

View full text Add to dashboard Cite

The invention of plastic film has brought not only convenience but also environmental pollution to people. To use natural vegetable fiber is the mainly approach to solve the problem. In this paper, the waste cotton fiber was used as raw material and the cotton nonwoven sample was made through wet laying process, after strengthened by chitosan, degradable film was prepared. The performances of the film were characterized and analyzed by testing the strength, air permeability, moisture permeability and other indexes. The results showed that chitosan can be used as strengthening agent, the performances of the film strengthened were improved, and it was degradable.

show abstract

“…Therefore, the main difference between the delayedcuring non-iron finishing and the conventional wrinkle finishing was the drying and curing finishing from the former. [4][5][6][7] In detail, the fabric was first padded with non-iron finishing agents, dried at low temperature, and then made into garments. The cross-linking reaction between finishing agents and garment was carried out under the high-temperature curing; the washable folds, creases, and surface smoothness were obtained; and the shape and ease of care properties of the garment improved.…”

Section: Introductionmentioning

confidence: 99%

Evaluation of Storage Stability for Delayed-Curing Non-Iron Finishing Sensitized Fabrics via Characteristic Group and Cross-linking Reaction Kinetics

Lou

Cai²,

Sun³

et al. 2023

AATCC Journal of Research

View full text Add to dashboard Cite

In delayed-curing and non-iron finishing, the sensitized fabric after low-temperature drying should have good surface planeness before curing at high temperatures, which implies that the finishing agent has not reacted with the cellulose fibers during storage; therefore, a suitable non-iron finishing agent is essential for achieving the above objectives. Meanwhile, there are currently no mature and efficient evaluation methods for the storage stability of sensitized fabrics. In this article, the content of characteristic groups of the sensitized fabrics with different storage conditions was measured. The storage time can be shortened from 30 to 6 days with high-temperature storage (40–60°C). The reaction kinetics equation was established under high-temperature storage; then using this equation to predict the cross-linking degree of sensitized fabrics during long-term storage at low temperature, the storage stability of sensitized fabrics can also be evaluated. The relative error of 2.5% between the predicted value and the measured value of the reaction degree showed the accuracy and effectiveness of the established method. This article provided a basis for the stability evaluation of the sensitized fabric and the selection of the finishing agent, finishing process, and storage conditions for the delayed-curing and non-ironing finishing process.

show abstract

Crosslinking of Sulfonated Cotton Cellulose

Cited by 8 publications

References 18 publications

New Method to Evaluate the Crosslinking Degree of Resin Finishing Agent with Cellulose Using Kjeldahl Method and Arrhenius Formula

New Method to Evaluate the Crosslinking Degree of Resin Finishing Agent with Cellulose Using Kjeldahl Method and Arrhenius Formula

Preparation and Analysis of Cotton Nonwoven Film Strengthened by Chitosan

Evaluation of Storage Stability for Delayed-Curing Non-Iron Finishing Sensitized Fabrics via Characteristic Group and Cross-linking Reaction Kinetics

Contact Info

Product

Resources

About