Crystal data for the spinels MGa₂O₄(M = Mg, Mn)

Towards a mechanistic understanding of the sol–gel syntheses of ternary carbides

“…With other transition metals, such as Mn, gallium tends to form oxides with the spinel structure. 29 Initially, it was attempted to describe the obtained PDF at 725 °C with a spinel structure where we placed Ga on all metal sites to simplify the model and the resulting fit is shown in Fig. 4(a).…”

Compressibility and structural stability of spinel-type MnIn2O4

“…Surprisingly, limited information is available about Mn 2 þ -M(IIIA) spinels (M(IIIA) ¼Ga 3 þ , Al 3 þ and In 3 þ ), those capable for cooperative paramagnetic and spin-liquid behavior. Among these spinels, MnAl 2 O 4 is the most studied one [17][18][19][20][21], for MnGa 2 O 4 a number of controversial results are reported [22][23][24][25][26] and the properties of MnIn 2 O 4 are addressed in only one study [27].…”

Site Preference of Cations and Structural Variation in MgAl2-xGaxO4 (0 ≤ x ≤ 2) Spinel Solid Solution

“…Casado and Rasines [12] determined the crystal structure of MgGa 2 O 4 using Xray powder diffraction method. AreaÂn and Trobajo-Fernandez [13] investigated cation distributions in the series of the solid solution Mg x Ni 1±x Ga 2 O 4 using Xray powder diffraction analyses.…”