Crystal growth and characterization of third order nonlinear optical piperazinium bis(4-hydroxybenzenesulphonate) (P4HBS) single crystal

Pichan, Karuppasamy; Muthu, Senthil Pandian; Ramasamy, P.

doi:10.1016/j.jcrysgro.2017.05.018

Cited by 83 publications

(9 citation statements)

References 81 publications

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“…The functional group assignment for the peaks raised in 1527 and 1336 cm −1 are the NO 2 asymmetrical and symmetrical stretching, respectively [27] . The presence of the aniline group is confirmed through NH 2 waging (728 cm −1 ) [28] . All the above vibrations quantitively ensure the formation of the novel DSNA ionic crystal.…”

Section: Morphology Within the Dsna Crystalmentioning

confidence: 84%

Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity

Anand

Rani

2023

ChemPhotoChem

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The idea of incorporating a novel counter anion group with the organic stilbazolium cation (C16H19N2+) yields a new third harmonic generation active single crystal of 4‐[2‐(4‐Dimethylamino‐phenyl)‐vinyl]‐1‐methyl‐pyridinium 2‐Nitroaniline‐4‐sulfonate (DSNA). The slow evaporation solution growth technique is employed to obtain DSNA crystals, whose nonlinear responses are analyzed through a continuous wave laser Z scan experiment. The thermally induced strong reverse saturation absorption and self‐defocusing behaviour of DSNA crystal infers the aptness of the material as an optical limiting device. Optical characterization outcomes imply that the lower absorption edge falls in the visible region (530 nm), with a broad transparency range of 0.53 to 1 μm. Exploration of other optical constants, extinction coefficient (k = 10‐4), emission wavelength (620 nm – red light), optical (σopt = 1010 Ωm‐1) and electrical conductivity (σelc = 1011 Ωm‐1) also concludes that DSNA crystal is a possible applicant for optoelectronic devices. The various bonds and corresponding lengths and angles involved in the formation of DSNA ionic crystal are evaluated by means of the Single Crystal X‐Ray Diffraction (SCXRD) technique. Linear and nonlinear optical property findings undoubtedly affirm that the titular DSNA crystal is an effectual Nonlinear Optical (NLO) crystal.

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Section: Morphology Within the Dsna Crystalmentioning

confidence: 84%

Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity

Anand

Rani

2023

ChemPhotoChem

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“…The increased intensity of emission can be used to detect organic organisms. The inclusion of electron-donating group NH and electrondrawing carboxylic group which might increase electron The third-order NLO characteristics of PPTSA sample were studied by Z-scan measurements to calculate the nonlinear absorption co-efficient (β), refractive index (n2), and susceptibility (χ 3 ) [25][26][27][28]. CW laser (532 nm) with a laser intensity of 100 mW was employed.…”

Section: Resultsmentioning

confidence: 99%

Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications

Balakrishnan

Priya

Lakshmanan

et al. 2023

Phys. Chem. Solid St.

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Piperazine (bis) p-toluenesulfonate (PPTSA), an organic single crystal was synthesized and grown at environmental temperature by slow evaporation process using methanol as the solvent. The grown PPTSA crystal is from the triclinic system and belongs to the space group P1-. Powder X-ray diffraction was performed to ensure lattice parameters. Analysis and confirmation of functional groups and bonds were carried out through FT-IR spectral study. The optical characteristics were investigated using the UV-Vis spectrum such as the optical absorption, cut-off wavelength were calculated. The photoluminescence investigation was conducted to assess the luminous characteristics of grown crystal. The calculated NLO parameters like β, n2, and χ(3) were found to be 0.0495×10-4 (cm/W), 8.705×10-10 (cm2/W), 5.316×10-7 (esu) and Optical Limiting threshold value was found to be 3.074×10-3 (Wcm-2). Antibacterial studies were carried out to investigate the biological significance against selected foodborne germs.

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“…Along with that, the low K value signifies that the grown ionic crystal can be used for the construction of devices, which are ideal for information processing and computing technology. 38 …”

Section: Resultsmentioning

confidence: 99%

“…Along with that, the low K value signies that the grown ionic crystal can be used for the construction of devices, which are ideal for information processing and computing technology. 38 3.3.2 Optical conductivity. Optical conductivity (s opt ) is the measure of the response of the material to the incident light frequency and it can be derived from eqn (4):…”

Section: Cation Group Absorptionmentioning

confidence: 99%

Analysis of the growth and physicochemical properties of the newly developed stilbazolium derivative 4-N,N-dimethylamino-4-N-methyl stilbazolium 2-formyl benzene sulfonate (DSFS) single crystal: an effective material for nonlinear optical applications

et al. 2022

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Crystal growth and characterization of third order nonlinear optical piperazinium bis(4-hydroxybenzenesulphonate) (P4HBS) single crystal

Cited by 83 publications

References 81 publications

Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity

Physicochemical and Nonlinear Optical Properties of a Stilbazolium Family Single Crystal with Third Order Nonlinear Optical Activity

Studies on structural, optical nonlinearity and antibacterial activity of Piperazine (bis) p-toluenesulfonate single crystal for optical limiting and biological applications

Analysis of the growth and physicochemical properties of the newly developed stilbazolium derivative 4-N,N-dimethylamino-4-N-methyl stilbazolium 2-formyl benzene sulfonate (DSFS) single crystal: an effective material for nonlinear optical applications

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