Crystal growth and characterization of a novel organometallic nonlinear-optical crystal:

Wang, X.Q; Xü, Dong; Lü, Mengkai; Yuan, Duorong; Xu, Shou-Xi; Guo, Shiyi; Zhang, Guanghui; Liu, J.R

doi:10.1016/s0022-0248(01)01012-0

Cited by 41 publications

(15 citation statements)

References 8 publications

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“…For a laser input pulse of 6.2mJ, the second harmonic signal (532nm) of 53mW and 636mW were obtained through urea and ZCTC respectively and thus confirming its second harmonic efficiency to be 12 times that of urea. Thus, the second harmonic generation efficiency of ZCTC is higher than the other organometallic crystals such as ATCC and FMTC but less than that of MMTC and MMTD [6][7][8][9].…”

Section: Resultsmentioning

confidence: 99%

Growth and characterization of non‐linear optical crystal ZnCd(SCN)₄

Joseph¹,

Rajarajan²,

Vimalan³

et al. 2007

Cryst. Res. Technol.

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Single crystals of ZCTC with dimension up to 5x2x3mm 3 were grown from aqueous solution by slow solvent evaporation method and the grown crystals were confirmed by single XRD and CHN analysis. The SHG efficiency of ZCTC was evaluated using Kurtz Perry technique. Its efficiency was found to be nearly 12 times that of urea when studied with the fundamental wavelength of 1064 nm. The mechanical properties of the grown crystal have been investigated by Vickers microhardness testing. The thermal parameters such as the thermal diffusivity (α), thermal effusivity (e), thermal conductivity (k) and heat capacity (c p ) of ZCTC were measured by an improved photopyroelectric (PPE) technique and the results were discussed. The TG/DTG studies reveal that the decomposition of the sample begins around 350°C. The photoconducting nature of ZCTC has also been investigated and reported.

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Section: Resultsmentioning

confidence: 99%

Growth and characterization of non‐linear optical crystal ZnCd(SCN)₄

Joseph¹,

Rajarajan²,

Vimalan³

et al. 2007

Cryst. Res. Technol.

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“…Bimetallic thiocyanate complexes like CdHg(SCN) 4 and MnHg(SCN) 4 have given a new dimension to the study of nonlinear optical crystal [9][10][11] .…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Characterization and Biological Studies of Some

Upadhayay¹

2013

Chem Sci Trans

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Abstract:The coordination chemistry of transition metal complexes has been progressing at a tremendous pace. These complexes were finding use in the field of homogeneous catalysis, analytical chemistry and biological system. The presence of thiocyanto group in mixed ligand coordinated complexes of transition metal was reported to have an ability to influence the biochemical behaviour of the complexes. Complexes of MM'(SCN) 4 (M = Co 2+ ; M' = Cd 2+ , Hg 2+ ) with N, N'-bis (benzylidene) -1, 2, phenylenediamine Schiff base of molecular formula [MM'(SCN) 4 (BENDAMB) (1, 2)] have been synthesized and characterized by elemental analyses, molar conductance magnetic moment, IR, electronic and 1 H NMR spectral studies. The softness parameter TEn ≠ of complexes have also been calculated to derive the binding side of the thiocyanate ligand. The insecticidal activity against Red cotton bug (Dysdercus koenigii) and antifungal activity against A.Flavus and F.Solani of complexes also been investigated and was compared with solvent and Schiff base.

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“…134.5˚C, molecular formula C 16 H 16 O 6 was isolated from ethyl acetate extract of the roots of the plant Prangos pabularia by column chromatography using silica gel as adsorbent. The structure of (a) was confirmed by comparison of its spectral data ( 1 H-NMR, 13 C-NMR, UV, IR and MS) with the data values reported in literature [18]. Compound (a) was subjected to acetylation with acetic anhydride and pyridine at room temperature to give compound Figure 1(b), m.p.…”

Section: Structural Analysismentioning

confidence: 74%

Structural, Thermal and Optical Studies of Oxypeucedanin Hydrate Monoacetate Micro-Crystals from <i>Prangos pabularia</i>

Banday¹,

Farooq²,

Farooq³

et al. 2012

AJAC

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Oxypeucedanin hydrate monoacetate (Mol. Formula = C 18 H 18 O 7 ) micro-crystals were obtained by acetylation of oxypeucedanin hydrate, a furanocoumarin, isolated from the roots of Prangos pabularia. The composition related structural, thermal and optical properties were investigated. All the crystals were found to have triclinic structure. From thermal studies of these crystals, stability, melting point and other relevant informations were obtained. Their blue emission, less absorption in entire visible range and band gap predicts these crystals as good candidate for modern optoelectronic devices.

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Crystal growth and characterization of a novel organometallic nonlinear-optical crystal:

Cited by 41 publications

References 8 publications

Growth and characterization of non‐linear optical crystal ZnCd(SCN)₄

Growth and characterization of non‐linear optical crystal ZnCd(SCN)₄

Synthesis, Characterization and Biological Studies of Some

Structural, Thermal and Optical Studies of Oxypeucedanin Hydrate Monoacetate Micro-Crystals from <i>Prangos pabularia</i>

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Crystal growth and characterization of a novel organometallic nonlinear-optical crystal:

Cited by 41 publications

References 8 publications

Growth and characterization of non‐linear optical crystal ZnCd(SCN)4

Growth and characterization of non‐linear optical crystal ZnCd(SCN)4

Synthesis, Characterization and Biological Studies of Some

Structural, Thermal and Optical Studies of Oxypeucedanin Hydrate Monoacetate Micro-Crystals from &lt;i&gt;Prangos pabularia&lt;/i&gt;

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Product

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Growth and characterization of non‐linear optical crystal ZnCd(SCN)₄

Growth and characterization of non‐linear optical crystal ZnCd(SCN)₄

Structural, Thermal and Optical Studies of Oxypeucedanin Hydrate Monoacetate Micro-Crystals from <i>Prangos pabularia</i>