Bismuth silicate Bi 4 Si 3 O 12 (BSO) crystal is a fast scintillator which has potential applications in high energy physics, nuclear physics, computed tomography and dosimetry. Compared with widely used Bi 4 Ge 3 O 12 (BGO) crystal, BSO has some better scintillation properties such as a faster decay time, greater radiation hardness and a lower raw material cost, so it is considered to be the substitute for an alternative to BGO crystals. However, two main problems hindered its practical applications: (1) it is difficult to grow large size and high quality crystals due to its compositional segregation; (2) BSO has a relatively low light yield. Recently, large size BSO crystals have been grown by the modified vertical Bridgman method in Shanghai Institute of Technology. The scintillation properties of rare earth doped BSO crystals have been investigated and BSO crystal doped with small amount Dy 2 O 3 increases its light yield remarkably. Furthermore, some experimental results revealed the potential applications of Re-doped BSO crystals in laser and LED fields. In this review, the growth process, scintillation properties and luminescent mechanism of Re or Ge doped BSO crystals were introduced. The spectroscopic properties and energy transfer of Re-doped BSO crystals were discussed based on its applications in laser and LED. As a result, doped BSO crystal is a novel multi-functional material for scintillation, laser and LED applications.