Crystal growth of Ba3BP3O12 with BPO4–NaF flux

Zhang, Zhijun; Wang, Hong; Hu, Guohong; Chen, Hao‐Hong; Yang, Xi; Jian-Gao, Zhao

doi:10.1016/j.jcrysgro.2010.01.035

Cited by 5 publications

(2 citation statements)

References 16 publications

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“…Tetrahedral groups such as BO 4 or PO 4 are excellent modules because they will effectively avoid layer habits, and their large energy gap is beneficial to deep UV transmission. − Traditionally, they are used to enrich the diversity of the crystal structure , and they rarely employed to design or synthesize deep-UV NLO materials owing to their habitually weak optical anisotropy. Birefringence determined by optical anisotropy is one of the indispensable properties for UV/deep-UV NLO materials because it is required for phase matching (PM) and determines coherent UV laser output, i.e., the shortest SHG PM wavelength.…”

Section: Introductionmentioning

confidence: 99%

Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials

et al. 2018

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Design of functional materials with targeted properties is a challenge because of the diversity of their potential structures. The functional performances of materials are mainly determined by the chemistry and electronic structure of modules consisting of local atomic groups with special arrangements. Tetrahedral modules are excellent modules for designing deep-ultraviolet/ultraviolet (UV) nonlinear optical (NLO) materials, but they are rarely favored due to their unpredictable optical anisotropy and second harmonic generation (SHG) response. In this work, we have developed a module-guided ab initio approach for evaluating the optical anisotropy of tetrahedral modules. The application of this method indicates that the tetrahedral modules with a specific arrangement will enhance the optical anisotropy of materials. With the functional modules consisting of tetrahedral modules and rare-earth cations, new high-performance rare-earth phosphates were assembled. These materials are promising deep-UV NLO materials because of their appropriate birefringences, large band gaps, moderate SHG responses, and easy to obtain large size crystals.

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Section: Introductionmentioning

confidence: 99%

Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials

et al. 2018

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“…During the process of exploring new crystals, the researchers paid much attention on borates due to their wide applications as nonlinear optical (NLO) materials, birefringent materials, and so on. The excellent performances of borates can originate from their abundant B−O structural frameworks including isolated clusters, one‐dimension (1D) chains, 2D layers or 3D networks constructed by BO 3 and BO 4 groups.…”

Section: Introductionmentioning

confidence: 99%

RbB₁₁O₁₆(OH)₂: First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System

Li²,

2019

ChemistrySelect

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A new hydroxyl rubidium borate, RbB11O16(OH)2, has been obtained in the sealed system. Its structure consists of a two‐dimensional layered anionic framework, which is composed of the fundamental building block, [B11O18(OH)2]5−. Detailed structural comparison with other hydroxyl rubidium borates indicates that RbB11O16(OH)2 is the first hydroxyl rubidium borate with a B−O layered structure. First‐principle theoretical studies have been conducted to help understand the electronic structure and its optical properties, and the results suggest that RbB11O16(OH)2 can be regarded as the potential birefringent crystal.

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Structural and optical properties of Cu(II) ions doped calcium borophosphate (CaBP) nanophosphor by solid-state synthesis

Yadav

Raja

Avinash

et al. 2015

J Mater Sci: Mater Electron

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Crystal growth of Ba3BP3O12 with BPO4–NaF flux

Cited by 5 publications

References 16 publications

Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials

Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials

RbB₁₁O₁₆(OH)₂: First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System

Structural and optical properties of Cu(II) ions doped calcium borophosphate (CaBP) nanophosphor by solid-state synthesis

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Crystal growth of Ba3BP3O12 with BPO4–NaF flux

Cited by 5 publications

References 16 publications

Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials

Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials

RbB11O16(OH)2: First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System

Structural and optical properties of Cu(II) ions doped calcium borophosphate (CaBP) nanophosphor by solid-state synthesis

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RbB₁₁O₁₆(OH)₂: First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System