Crystal structure and energy transfer of trans-RSSR-[CrCl2(cyclam)]3[Cr(CN)6]·14H2O

Flores-Álamo, Marcos; Sosa‐Torres, Martha E.; Toscano, Rubén A.; Camarillo, E.; Hernández, José Manuel; Murrieta, H.

doi:10.1016/j.inoche.2004.07.021

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Cited by 7 publications

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“…It has been observed that the reactivity of the peroxo complexes depend on the nature of other auxiliary ligands used. Peroxo complexes containing monodentate and bidentate auxiliary ligands were found to be undergoes oxygen transfer reactions [21][22][23], those containing tridenate and quadridenate ligands were inert towards oxidation reaction [24].…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Characterization of the Peroxo Complexes of Uranium (VI) Containing Organic Acids and Amine Bases Ligands

Nasrin¹

2015

IJMSA

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-1 , indicating that the dioxygen moieties are bonded on "side-on" fashion with the U(VI). The magnetic moment values indicated that these complexes were diamagnetic in nature suggesting no changes in the oxidation states of the metal ions upon complexation. These data also consistent with eight fold coordination of U(VI). The electronic spectral data of the complexes showed bands in between 315-380 nm due to the charge transfer band only.

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