Crystal structure and Hirshfeld surface analysis of dimethyl (3aS,6R,6aS,7S)-2-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isoquinoline-3a1,6a-dicarboxylate

Atioğlu, Zeliha; Akkurt, Mehmet; Toze, Flavien A. A.; Dorovatovskii, Pavel V.; Guliyeva, Narmina; Panahova, Humay M.

doi:10.1107/s2056989018014305

Acta Cryst E

2018

DOI: 10.1107/s2056989018014305

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Crystal structure and Hirshfeld surface analysis of dimethyl (3aS,6R,6aS,7S)-2-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isoquinoline-3a¹,6a-dicarboxylate

Zeliha Atioğlu

Mehmet Akkurt

Flavien A. A. Toze

et al.

Abstract: In the molecular structure of the title compound, two dihydrofuran and two tetrahydrofuran rings as well as one piperidine ring are fused together. In the crystal, molecules are linked by C—H⋯O and C—H⋯F hydrogen bonds, forming a three-dimensional network.

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Crystal structure and Hirshfeld surface analysis of dimethyl (1R,3aS,3a¹ R,6aS,9R,9aS)-3a¹,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate

Alekseeva¹,

Raspertov²,

Çelikesir³

et al. 2019

Acta Cryst E

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The title diepoxyphenalene derivative, C17H18O6, comprises a fused cyclic system containing four five-membered rings (two dihydrofuran and two tetrahydrofuran) and one six-membered ring (cyclohexane). The five-membered dihydrofuran and tetrahydrofuran rings adopt envelope conformations, and the six-membered cyclohexane ring adopts a distorted chair conformation. Two methyl carboxylate groups occupy adjacent positions (2- and 3-) on a tetrahydrofuran ring. In the crystal, two pairs of C—H...O hydrogen bonds link the molecules to form inversion dimers, enclosing two R 2 2(6) ring motifs, that stack along the a-axis direction and are arranged in layers parallel to the bc plane.

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Crystal structure and Hirshfeld surface analysis of dimethyl (1R,3aS,3a¹ R,6aS,9R,9aS)-3a¹,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate

Alekseeva¹,

Raspertov²,

Çelikesir³

et al. 2019

Acta Cryst E

Self Cite

View full text Add to dashboard Cite

show abstract

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Crystal structure and Hirshfeld surface analysis of dimethyl (3aS,6R,6aS,7S)-2-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isoquinoline-3a¹,6a-dicarboxylate

Abstract: In the molecular structure of the title compound, two dihydrofuran and two tetrahydrofuran rings as well as one piperidine ring are fused together. In the crystal, molecules are linked by C—H⋯O and C—H⋯F hydrogen bonds, forming a three-dimensional network.

Cited by 1 publication

References 20 publications

Crystal structure and Hirshfeld surface analysis of dimethyl (1R,3aS,3a¹ R,6aS,9R,9aS)-3a¹,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate

Crystal structure and Hirshfeld surface analysis of dimethyl (1R,3aS,3a¹ R,6aS,9R,9aS)-3a¹,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate

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Crystal structure and Hirshfeld surface analysis of dimethyl (3aS,6R,6aS,7S)-2-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isoquinoline-3a1,6a-dicarboxylate

Abstract: In the mol­ecular structure of the title compound, two di­hydro­furan and two tetra­hydro­furan rings as well as one piperidine ring are fused together. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯F hydrogen bonds, forming a three-dimensional network.

Cited by 1 publication

References 20 publications

Crystal structure and Hirshfeld surface analysis of dimethyl (1R*,3aS*,3a1 R*,6aS*,9R*,9aS*)-3a1,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate

Crystal structure and Hirshfeld surface analysis of dimethyl (1R*,3aS*,3a1 R*,6aS*,9R*,9aS*)-3a1,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate

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Crystal structure and Hirshfeld surface analysis of dimethyl (3aS,6R,6aS,7S)-2-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H,6H,7H-3a,6:7,9a-diepoxybenzo[de]isoquinoline-3a¹,6a-dicarboxylate

Abstract: In the molecular structure of the title compound, two dihydrofuran and two tetrahydrofuran rings as well as one piperidine ring are fused together. In the crystal, molecules are linked by C—H⋯O and C—H⋯F hydrogen bonds, forming a three-dimensional network.

Crystal structure and Hirshfeld surface analysis of dimethyl (1R,3aS,3a¹ R,6aS,9R,9aS)-3a¹,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate

Crystal structure and Hirshfeld surface analysis of dimethyl (1R,3aS,3a¹ R,6aS,9R,9aS)-3a¹,5,6,9a-tetrahydro-1H,4H,9H-1,3a:6a,9-diepoxyphenalene-2,3-dicarboxylate