2021
DOI: 10.1107/s2056989021008033
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Crystal structure and Hirshfeld surface analysis study of (E)-1-(4-chlorophenyl)-N-(4-ferrocenylphenyl)methanimine

Abstract: The substituted cyclopentadienyl ring in the title molecule, [Fe(C5H5)(C18H13ClN)], is nearly coplanar with the phenyl-1-(4-chlorophenyl)methanimine substituent, with dihedral angles between the planes of the phenylene ring and the Cp and 4-(chlorophenyl)methanimine units of 7.87 (19) and 9.23 (10)°, respectively. The unsubstituted cyclopentadienyl ring is rotationally disordered, the occupancy ratio for the two orientations refined to a 0.666 (7)/0.334 (7) ratio. In the crystal, the molecules pack in `bilayer… Show more

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Cited by 3 publications
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“…We were especially pleased to see that four of the articles had direct contributions from Jerry himself, as well as some of his former students and postdocs from Keene State College. The topical coverage of the articles spans the full spectrum of non-biological crystallography, including organic and main-group compounds (Thiruvalluvar et al, 2021;Mahesha et al, 2021;Allah et al, 2021;Malla et al, 2022;Rajegowda et al, 2021;Purdy et al, 2021), complexes of transition metals and lanthanides (Addison et al, 2022;Frey et al, 2021;Ullery et al, 2021;Sghyar et al, 2021;Tinapple et al, 2021;Mikhalyova et al, 2022;Pavlischuk et al, 2021), transition metal and actinide clusters (Park et al, 2022;Patel et al, 2022;Kelley et al, 2021), and coordination polymers (Lobana et al, 2022). It also includes two articles (Foxman, 2021;Zheng & Campbell, 2021) first published as part of the 'Modern approaches and tools for teaching crystallography' special issue in Acta E that describe the tutorial for teaching space groups and crystallographic symmetry that Jerry developed with Bruce Foxman.…”
mentioning
confidence: 99%
“…We were especially pleased to see that four of the articles had direct contributions from Jerry himself, as well as some of his former students and postdocs from Keene State College. The topical coverage of the articles spans the full spectrum of non-biological crystallography, including organic and main-group compounds (Thiruvalluvar et al, 2021;Mahesha et al, 2021;Allah et al, 2021;Malla et al, 2022;Rajegowda et al, 2021;Purdy et al, 2021), complexes of transition metals and lanthanides (Addison et al, 2022;Frey et al, 2021;Ullery et al, 2021;Sghyar et al, 2021;Tinapple et al, 2021;Mikhalyova et al, 2022;Pavlischuk et al, 2021), transition metal and actinide clusters (Park et al, 2022;Patel et al, 2022;Kelley et al, 2021), and coordination polymers (Lobana et al, 2022). It also includes two articles (Foxman, 2021;Zheng & Campbell, 2021) first published as part of the 'Modern approaches and tools for teaching crystallography' special issue in Acta E that describe the tutorial for teaching space groups and crystallographic symmetry that Jerry developed with Bruce Foxman.…”
mentioning
confidence: 99%