2022
DOI: 10.3390/app12031181
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Crystal Structure, Electrical Conductivity and Hydration of the Novel Oxygen-Deficient Perovskite La2ScZnO5.5, Doped with MgO and CaO

Abstract: This paper demonstrates the possibility of creating oxygen deficiency in perovskites A+3B+3O3 by introducing two types of cations with different charges into the B-sublattice. For this, it is proposed to introduce a two-charged cation, for example, Zn2+, as an alternative to alkaline earth metals. Previously, this possibility was demonstrated for aluminate LaAlO3 and indate LaInO3. In this article, we have focused on the modification of the scandium-containing perovskite LaScO3. The novel oxygen-deficient pero… Show more

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Cited by 10 publications
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“…[23][24][25] The excellent reactivity of metal oxides is endorsed to unsaturated oxygen deficient sites. 26 Blending of two metal oxides lead to hetro-metal bond formation due to orbital hybridization and charge transfer between metals. 27,28 Such an advancement in catalyst engineering enhance the catalytic efficiency of materials to significant extent.…”
Section: Lis Of Symbolsmentioning
confidence: 99%
“…[23][24][25] The excellent reactivity of metal oxides is endorsed to unsaturated oxygen deficient sites. 26 Blending of two metal oxides lead to hetro-metal bond formation due to orbital hybridization and charge transfer between metals. 27,28 Such an advancement in catalyst engineering enhance the catalytic efficiency of materials to significant extent.…”
Section: Lis Of Symbolsmentioning
confidence: 99%