Crystal structure of 1,1-bis(η ⁵-adamantylcyclopentadienyl)-3-phenyl-2-trimethylsilyl-2,3-dihydroisotitanazole, C₄₂H₅₅NSiTi

Abstract

CCDC no.: 1543470The asymmetric unit of the title crystal structure is shown in the figure. Hydrogen atoms are omitted for clarity. Tables 1 and 2 contain details of the measurement method and a list

From Five to Seven: Ring Expansion of Monoazadiene Titanium Complexes by Insertion of Aldehydes, Ketones and Nitriles

“…The four‐membered rings exist as azatitanacyclobutanes IVa or ‐butenes IVb, which can be generated via [2+2] cycloaddition reactions of olefins or alkynes– and titanium imido species, or by employing titanium carbenes and carbodiimides . The family of the five‐membered rings is represented by insertion products of olefins and acetylenes into titanaaziridines, leading to azatitanacylopentanes Va and −3‐pentenes Vb ,. The isomeric azatitanacyclo‐2‐pentenes Vc are formed by complexation of 1‐azabutadiene ligands .…”