Crystal structure of 1-mesityl-3-methyl-4-phenyl-1H-1,2,3-triazol-3-ium iodide

Abstract

In the cation of the title salt, C18H20N3 +·I−, the mesityl and phenyl rings are inclined to the central triazolium ring by 61.39 (16) and 30.99 (16)°, respectively, and to one another by 37.75 (15)°. In the crystal, mol­ecules are linked via C—H⋯I hydrogen bonds, forming slabs parallel to the ab plane. Within the slabs there are weak π–π inter­actions present involving the mesityl and phenyl rings [inter-centroid distances are 3.8663 (18) and 3.8141 (18) Å].

Crystal structure and Hirshfeld surface analysis of 4-azido-2-(3,5-dimethylphenyl)-5-(4-nitrophenyl)-2H-1,2,3-triazole

“…The ten most similar compounds found in a search of the Cambridge Structural Database (CSD, Version 5.42, update of September 2021; Groom et al, 2016) for the 2H-1,2,3-triazole group are JADSEP (Canseco-Gonza ´lez et al, 2015), JELTEC (Zukerman-Schpector et al, 2017), HUYTEC (Haslinger et al, 2015), FEVLIE, FEVLOK, FEVLUQ, FEVMAX, FEVMEB and FEVMOL (Farra ´n et al, 2018) and SECQUO (Altimari et al, 2012).…”