1998
DOI: 10.1524/ncrs.1998.213.14.613
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Crystal structure of 2,2'-dipyridylbis(triphenylphosphine)dihydroiridium( III) triflate dichloromethane solvate, [Ir(bру)(РhзР)2Н2]+[СFзSOз]∞·CH2Cl2

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Cited by 2 publications
(8 citation statements)
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“…Pignolet et al. , and Crabtree et al . previously reported the syntheses of complexes 1a − c . 1a was obtained by the reaction of the bis-solvento complex [Ir(PPh 3 ) 2 (acetone) 2 (H) 2 ]BF 4 and 2,2‘-bipyridyl, and 1b by metathesis of 1a with NH 4 PF 6 . , Here, we report a modified procedure for the preparation of complexes 1 and 2 .…”
Section: Resultsmentioning
confidence: 99%
“…Pignolet et al. , and Crabtree et al . previously reported the syntheses of complexes 1a − c . 1a was obtained by the reaction of the bis-solvento complex [Ir(PPh 3 ) 2 (acetone) 2 (H) 2 ]BF 4 and 2,2‘-bipyridyl, and 1b by metathesis of 1a with NH 4 PF 6 . , Here, we report a modified procedure for the preparation of complexes 1 and 2 .…”
Section: Resultsmentioning
confidence: 99%
“…integer spacing. The structures of 1 were additionally fully corroborated in solution using by a combination of 1 H, 13 . Gratifyingly, we were also been able to grow single crystals of 1b and elucidate its solid-state structure using X-ray diffraction.…”
Section: H Nmr Spectrum Associated With the Formation Of 3•db24c8mentioning
confidence: 89%
“…1). 12,13 Notably there is no meaningful steric buttressing apparent from close proximity of the interlocked db24c8 to the metal fragment (Ir1⋯N15, 6.540(2) Å), evident for example by the similarity of P31-Ir1-P51 bond angles in 1a (165.76(3)°) to those observed in 4b[BAr Fourier difference map, and the presence of two strong hydrogen bonds between the ammonium cation and ether linkages of db24c8 (N15-O71, 3.057(3); N15-O77, 3.030(3) Å).…”
Section: H Nmr Spectrum Associated With the Formation Of 3•db24c8mentioning
confidence: 99%
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