Abstract:C 34 H 40 N 6 NiO 12 S, triclinic, P1 (no. 2), a =10.3678(4) Å, b =13.3201(6) Å, c =14.1062(7) Å, a =106.309(4)°, b =100.936(4)°, g =93.503(3)°, V =1822.2 Å 3 , Z =2,
“…Sulfonamide and its derivatives have attracted wide attention due to their various biological activities, such as antibacterial [5,6], antiviral [7,8], antimalarial [9,10] and anticancer [8,11]. In addition, N and O atoms in the structure can be used as electron donors for coordination bonds, which may result in different coordination modes [12,13], which facilitates the construction of metal-organic coordination polymers. In recent years, sulfonamide and its derivatives have been widely used to construct metal-organic coordination polymers [14,15].…”
“…Sulfonamide and its derivatives have attracted wide attention due to their various biological activities, such as antibacterial [5,6], antiviral [7,8], antimalarial [9,10] and anticancer [8,11]. In addition, N and O atoms in the structure can be used as electron donors for coordination bonds, which may result in different coordination modes [12,13], which facilitates the construction of metal-organic coordination polymers. In recent years, sulfonamide and its derivatives have been widely used to construct metal-organic coordination polymers [14,15].…”
“…The structures of metal coordination polymers can be formed by coordination bonds and by weak interactions (such as hydrogen bonding and π-π stacking interaction) [12][13][14]. The molecular structure of the N-sulfonamidic acid derivatives contain multiple groups that can participate in coordination, which is beneficial to the formation of metal-organic coordination polymers [15]. The asymmetric unit is composed of one independent Cu(II) ion, one nbs ligand, one 2,2′-bipy ligand, one coordinated water molecules and two lattice water molecules.…”
“…The sulfonylated amino acid has a plurality of coordination sites because it contains both an amino group and a carboxyl group. It can be used to assemble MOFs and CPs [5][6][7][8] which have potential applications in gas adsorption and separations [9][10][11], sensors [12,13], catalysis [14,15], and fluorescent materials [16].…”
C18H14NiN4O6S, trigonal, R3̄ (no. 148), a = 31.014(11) Å, b = 31.014(11) Å, c = 10.125(7) Å, V = 8434(8) Å3, Z = 18, Rgt(F) = 0.0380, wRref(F2) = 0.0941, T = 296(2) K.
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