Crystal structure of a palladium(II) complex containing the wide bite-angle bis(selenium) ligand, cis-[(
 t
 BuNH)(Se)P(μ-N
 t
 Bu)2P(Se)(NH
 t
 Bu)]

Bonnette, Austin; Mague, Joel T.; Chandrasekaran, P.

doi:10.1107/s2056989018000841

Acta Cryst E

2018

DOI: 10.1107/s2056989018000841

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Crystal structure of a palladium(II) complex containing the wide bite-angle bis(selenium) ligand, cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

Austin Bonnette

Joel T. Mague

P. Chandrasekaran

Abstract: A palladium(II) complex {systematic name: dichlorido [1,3-di-tert-butyl-2,4-bis(tert-butylamino) . In the crystal, the molecules are interlinked through weak N-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen-bonding interactions.

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2024

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Mercury(II) halide complex of cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

Selby-Karney,

Sampath,

Arumugam

et al. 2024

Acta Crystallogr E Cryst Commun

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The mercury(II) halide complex [1,3-di-tert-butyl-2,4-bis(tert-butylamino)-1,3,2λ5,4λ5-diazadiphosphetidine-2,4-diselone-κ2 Se,Se′]diiodidomercury(II) N,N-dimethylformamide monosolvate, [HgI2(C16H38N4P2Se2)]·C3H7NO or (1)HgI2, 2, containing cis-[( t BuNH)(Se)P(μ-N t Bu)2P(Se)(NH t Bu)] (1) was synthesized and structurally characterized. The crystal structure of 2 confirms the chelation of chalcogen donors to HgI2 with a natural bite angle of 112.95 (2)°. The coordination geometry around mercury is distorted tetrahedral as indicated by the τ4 geometry index parameter (τ4 = 0.90). In the mercury complex, the exocyclic tert-butylamido substituents are arranged in an (endo, endo) fashion, whereas in the free ligand (1), the exocyclic substituents are arranged in an (exo, endo) pattern. Compound 2 displays non-classical N—H...O hydrogen-bonding interactions with the solvent N,N-dimethylformamide. These interactions may introduce geometrical distortion and deviation from an ideal geometry. An isostructural HgBr2 analogue containing cis-[( t BuNH)(S)P(μ-N t Bu)2P(S)(NH t Bu)] was also synthesized and structurally characterized, CIF data for the compound being presented as supporting information.

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Mercury(II) halide complex of cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

Selby-Karney,

Sampath,

Arumugam

et al. 2024

Acta Crystallogr E Cryst Commun

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Crystal structure of a palladium(II) complex containing the wide bite-angle bis(selenium) ligand, cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

Abstract: A palladium(II) complex {systematic name: dichlorido [1,3-di-tert-butyl-2,4-bis(tert-butylamino) . In the crystal, the molecules are interlinked through weak N-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen-bonding interactions.

Cited by 1 publication

References 14 publications

Mercury(II) halide complex of cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

Mercury(II) halide complex of cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

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Crystal structure of a palladium(II) complex containing the wide bite-angle bis(selenium) ligand, cis-[( t BuNH)(Se)P(μ-N t Bu)2P(Se)(NH t Bu)]

Abstract: A palladium(II) complex {systematic name: dichlorido [1,3-di-tert-butyl-2,4-bis(tert-butylamino) . In the crystal, the molecules are interlinked through weak N-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen-bonding interactions.

Cited by 1 publication

References 14 publications

Mercury(II) halide complex of cis-[( t BuNH)(Se)P(μ-N t Bu)2P(Se)(NH t Bu)]

Mercury(II) halide complex of cis-[( t BuNH)(Se)P(μ-N t Bu)2P(Se)(NH t Bu)]

Contact Info

Product

Resources

About

Crystal structure of a palladium(II) complex containing the wide bite-angle bis(selenium) ligand, cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

Mercury(II) halide complex of cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]

Mercury(II) halide complex of cis-[(^tBuNH)(Se)P(μ-N^tBu)₂P(Se)(NH^tBu)]