Crystal structure of aqua-(5-nitrosalicylato-κ² O,O′)-(1,10-phenanthroline-κ² N,N′)copper(II), C₁₉H₁₃CuN₃O₆

Abstract

CCDC no.: 1456393The asymmetric unit of the title crystal structure is shown in the gure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Source of materialA mixture of Cu(NO 3 ) 2 ·4H 2 O (0.1 mmol), phenanthroline(phen) (0.1 mmol), 5-nitrosalicylic acid (0.2 mmol) and distilled water (10 mL) was added into a Te on-lined autoclave (20 mL) and heated at 180°C for 72 h. Green chunklike crystals of the title complex were collected from the reaction mixture.

Crystal structure of diaqua-bis(μ2-5-chloro-salicylato-κ3 O,O′:O′)-bis(5-chloro-salicylato-κ2 O,O′)-bis(1,10-phenanthroline-κ2 N,N′) dilead(II) – water (1/2), C52H36C14N4O14Pb2·2(H2O)

“…Salicylic acid (H 2 sal) and deprotonated derivatives are used as carboxylate ligands [4,5]. 1,10-Phenanthroline (phen) often acts as a chelating ligand for its high affinity to metal ions and also plays an important role in the development of supramolecular chemistry [6,7].…”