Abstract:2-Mercaptothiazolate is generally used as a monodentate and bridging ligand. We report here the crystal structure of a new type of nickel(II) complex in which the 2-mercaptothiazolate ligand acts as a chelating and non-bridging ligand.
Cytotoxicity in cancer cells with structure activity relationship has been explored in isostructural Co(ii) and Zn(ii) compounds involving energetically significant cooperative (π–π)2/(π–π)1/(π–π)2 assemblies and fascinating (H2O)21 clusters.
Cytotoxicity in cancer cells with structure activity relationship has been explored in isostructural Co(ii) and Zn(ii) compounds involving energetically significant cooperative (π–π)2/(π–π)1/(π–π)2 assemblies and fascinating (H2O)21 clusters.
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