Crystal structure of bis{1-[(E)-(2-methoxyphenyl)diazenyl]naphthalen-2-olato-κ³O,N²,O′}copper(II) containing an unknown solvate

Abstract

The title complex, [Cu(C17H13N2O2)2], crystallizes with two independent mol­ecules in the asymmetric unit. Each CuII atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olate ligands. In the crystal, the two mol­ecules are linked via weak C—H⋯O hydrogen bonds which in turn stack parallel to [010]. A region of disordered electron density, most probably disordered methanol solvent molecules, was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Acta Cryst. C71, 9–18]. Their formula mass and unit-cell characteristics were not taken into account during refinement.

Tautomerization of diazene<=>hydrazine via single proton tautomerization, spectral, XRD/HSA-interactions, optical and DFT/TD-DFT of new hydrazine ligand

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“…They have many practical applications such as the coloring of diverse materials, the dyeing of textile fibers, colored polymers and plastics, medicinal-biological, and advanced applications in organic syntheses [2][3][4][5]. Lately, they have attracted attention in coordination chemistry [6][7][8][9]. They are also used in the fields of optical data storage and nonlinear optics [10][11][12][13].…”