Crystal Structure of Bis(&lt;i&gt;O&lt;/i&gt;-Propyldithiocarbonato-&lt;i&gt;κ&lt;/i&gt;&lt;sup&gt;2&lt;/sup&gt;&lt;i&gt;S&lt;/i&gt;,&lt;i&gt;S&lt;/i&gt;′)(2,2′-bipyridine-&lt;i&gt;κ&lt;/i&gt;&lt;sup&gt;2&lt;/sup&gt;&lt;i&gt;N&lt;/i&gt;,&lt;i&gt;N&lt;/i&gt;′)nickel(II)

Singh, K. C.; Kapoor, Sanjay; Sachar, Renu; Gupta, Vivek K.; Rajnikant,

doi:10.2116/xraystruct.28.43

Cited by 4 publications

(1 citation statement)

References 6 publications

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“…The Ni-S bond lengths involving the xanthate ligands are 2.440(9)Å for Ni1-S1 and 2.433(1)Å for Ni1-S2. The bond angles in the pyridine ring vary from 117.0(3) to 123.8(3) ∘ , with the average value being 119.9(8) ∘ , and these values of bond angles and bond distances are in good agreement with those reported for other analogous Ni-dithiocarbonato complexes [30][31][32]. The C-S bond lengths involving the xanthate ligands are S1-C3 = 1.691(4) and S2-C3 = 1.691(4)Å.…”

Section: Description Of the Crystal Structuresupporting

confidence: 85%

Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ²S,S′)bis(4-cyanopyridine-κN)nickel(II)

Singh

Kapoor

Sachar

et al. 2014

Journal of Crystallography

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The [Ni(S2CO-n-C5H11)2(C6H4N2)2] adduct of 4-cyanopyridine with [Ni(S2CO-n-C5H11)2] was synthesized and characterized by elemental analysis, magnetic susceptibility measurement, IR, electronic spectral data, and X-ray diffraction analysis. The Ni atom in the title complex is octahedrally coordinated within a trans-N2S4 donor set, with the Ni atom located on a centre of inversion. The title compound exhibits magnetic moment value (3.20 B.M) which is in agreement with magnetic moment values observed for paramagnetic octahedral complexes of nickel(II). The title complex crystallizes in the orthorhombic space group Pbca with unit cell parameters a = 11.455(5), b = 9.602(4), and c = 26.374(1) Å. Crystal structure was solved by direct methods and refined by full matrix least-squares procedures to a final R value of 0.0499 for 2004 observed reflections. The amyl chain is disordered over two sets of sites, with occupancy ratios of 0.595 : 0.405. Infinite long chains of molecules are formed with the help of C–H⋯N hydrogen bond.

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Section: Description Of the Crystal Structuresupporting

confidence: 85%

Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ²S,S′)bis(4-cyanopyridine-κN)nickel(II)

Singh

Kapoor

Sachar

et al. 2014

Journal of Crystallography

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Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2]

Juncal

Ferrer

Williams

et al. 2022

Chemical Physics Letters

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Synthesis and characterization of the adducts of bis(O-butylxanthato)Ni(II) with nitrogen donor ligands and X-ray structure of bis(O-butylxanthato)bis(3-chloropyridine)nickel(II)

Kour

Sachar

et al. 2017

Journal of Molecular Structure

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Crystal Structure of Bis(<i>O</i>-Propyldithiocarbonato-<i>κ</i><sup>2</sup><i>S</i>,<i>S</i>′)(2,2′-bipyridine-<i>κ</i><sup>2</sup><i>N</i>,<i>N</i>′)nickel(II)

Cited by 4 publications

References 6 publications

Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ²S,S′)bis(4-cyanopyridine-κN)nickel(II)

Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ²S,S′)bis(4-cyanopyridine-κN)nickel(II)

Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2]

Synthesis and characterization of the adducts of bis(O-butylxanthato)Ni(II) with nitrogen donor ligands and X-ray structure of bis(O-butylxanthato)bis(3-chloropyridine)nickel(II)

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Crystal Structure of Bis(<i>O</i>-Propyldithiocarbonato-<i>κ</i><sup>2</sup><i>S</i>,<i>S</i>′)(2,2′-bipyridine-<i>κ</i><sup>2</sup><i>N</i>,<i>N</i>′)nickel(II)

Cited by 4 publications

References 6 publications

Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ2S,S′)bis(4-cyanopyridine-κN)nickel(II)

Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ2S,S′)bis(4-cyanopyridine-κN)nickel(II)

Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2]

Synthesis and characterization of the adducts of bis(O-butylxanthato)Ni(II) with nitrogen donor ligands and X-ray structure of bis(O-butylxanthato)bis(3-chloropyridine)nickel(II)

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Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ²S,S′)bis(4-cyanopyridine-κN)nickel(II)

Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ²S,S′)bis(4-cyanopyridine-κN)nickel(II)