Crystal structure of bis((pyrazin-2-ylmethyl)(pyrazine-2-carbonyl)amido-κ3
 N,N′,N′′)copper(II), C20H16CuN10O2

Wang, Zhaodong; Xu, Qiang; Ni, Haitao; Liu, Xidong

doi:10.1515/ncrs-2017-0069

Zeitschrift Für Kristallographie - New Crystal Structures

2017

DOI: 10.1515/ncrs-2017-0069

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Crystal structure of bis((pyrazin-2-ylmethyl)(pyrazine-2-carbonyl)amido-κ³ N,N′,N′′)copper(II), C₂₀H₁₆CuN₁₀O₂

Zhaodong Wang

Qiang Xu

Haitao Ni

et al.

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2021

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Synthesis and Structure of the Copper Complex[Cu₂L₂^ox(SO₄)(H₂O)₄](H₂O)₄

Wang

2021

E3S Web Conf.

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The reaction of N-(pyridine-2-ylmethyl)pyrazine-2-carboxamide (HL) and copper(II) sulfate leads to the formation of a new copper complex, [Cu2L2ox(SO4)(H2O)4](H2O)4(1), in which the deprotonated amide L-ligand was oxidized to a imide Lox-exposed to the air in the presence of the Cu ion. The X-ray crystal analysis reveals that it consists of two mononuclear copper unit with different coordination modes, multiple O-H…O hydrogen bonding between water molecules or water and sulfate O atom to form 3D networks. CCDC: 2088935,1.

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Synthesis and Structure of the Copper Complex[Cu₂L₂^ox(SO₄)(H₂O)₄](H₂O)₄

Wang

2021

E3S Web Conf.

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Crystal structure of bis((pyrazin-2-ylmethyl)(pyrazine-2-carbonyl)amido-κ³ N,N′,N′′)copper(II), C₂₀H₁₆CuN₁₀O₂

Cited by 1 publication

References 8 publications

Synthesis and Structure of the Copper Complex[Cu₂L₂^ox(SO₄)(H₂O)₄](H₂O)₄

Synthesis and Structure of the Copper Complex[Cu₂L₂^ox(SO₄)(H₂O)₄](H₂O)₄

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Crystal structure of bis((pyrazin-2-ylmethyl)(pyrazine-2-carbonyl)amido-κ3 N,N′,N′′)copper(II), C20H16CuN10O2

Cited by 1 publication

References 8 publications

Synthesis and Structure of the Copper Complex[Cu2L2ox(SO4)(H2O)4](H2O)4

Synthesis and Structure of the Copper Complex[Cu2L2ox(SO4)(H2O)4](H2O)4

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Product

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Crystal structure of bis((pyrazin-2-ylmethyl)(pyrazine-2-carbonyl)amido-κ³ N,N′,N′′)copper(II), C₂₀H₁₆CuN₁₀O₂

Synthesis and Structure of the Copper Complex[Cu₂L₂^ox(SO₄)(H₂O)₄](H₂O)₄

Synthesis and Structure of the Copper Complex[Cu₂L₂^ox(SO₄)(H₂O)₄](H₂O)₄