Crystal structure of bis(triphenylphospine-kP)-dichloropalladium( II) —acetonitrile (1:1), [PdCl2(C18H15P)2] · CH3CN

Cui, Lina; Li, Zhongfeng; Wen, Jin; Jiang, Ye; Jin, Qiong‐Hua; Gong, Huili

doi:10.1524/ncrs.2011.0265

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“…The bond distances d(Pd-Cl) = 2.381(2) Å / 2.316(2) Å are similar to those in [PdCl 2 (PPh 3 ) 2 ]·CH 3 CN [3] and the Pd-P distance (2.253(2) Å) is shorter than the corresponding distance in [PdCl 2 (PPh 3 ) 2 ]·2CHCl 3 (2.293(2) Å) [6]. The distortion from tetragonal-planar coordination around the Pd(II) atoms, is also confirmed by the following angles: P(1) …”

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Crystal structure of dichlorido-(6-methyl-1H-benzo[d]imidazole-2-thiolo κS)-(triphenylphosphine-κP)palladium(II)-methanol monosolvate (1:1), [PdCl2(C8H8N2S)(C18H15P)]·CH3OH, C27H27Cl2N2OPPdS

Qiu

Liu

et al. 2013

Zeitschrift Für Kristallographie - New Crystal Structures

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Source of materialA mixture of PdCl 2 (0.2mmol) and 6-methyl-1H-benzo[d]-imidazole-2-thiole (mbitH) (0.2 mmol) in MeOH and CH 2 Cl 2 (10mL, v/v = 1:1) was stirred for 2h and then PPh 3 (0.2mmol) was added to the mixture which was stirred for another 4h. The insoluble residues were removed by filtration, and the filtrate was evaporated slowly at room temperature for a week to yield red, crystalline products. DiscussionThe chemistry of palladium(II) complexes is of considerable interest due to their potential applications in organic synthesis, catalysis and photo-physical chemistry [1][2][3]. The ligand mbitH molecule, with one -SH and two potential coordination nitrogen atoms, is excellent in building supramolecular structures [4,5]. However, to our best knowledge, the palladium(II) complex with mbit has not been reported. In the title complex, Pd atom is coor-

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confidence: 60%

“…The chemistry of palladium(II) complexes is of considerable interest due to their potential applications in organic synthesis, catalysis and photo-physical chemistry [1][2][3]. The ligand mbitH molecule, with one -SH and two potential coordination nitrogen atoms, is excellent in building supramolecular structures [4,5].…”

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confidence: 99%