Crystal structure of bis(μ₂-2-fluorobenzoato-κ² O:O:O′) bis(μ₂-2-fluorobenzoato-κ² O:O′)dinitrato-κ² O,O′ bis(1,10-phenathroline-κ² N,N′)diterbium(III), C₅₂H₃₂F₄N₆O₁₄Tb₂

Abstract

C52H32F4N6O14Tb2, triclinic, P1̅ (no. 2), a = 10.745(2) Å, b = 10.993(2) Å, c = 11.141(2) Å, α = 84.45(3)°, β = 81.22(3)°, γ = 69.46(3)°, V = 1216.6(4) Å3, Z = 1, Rgt(F) = 0.0345, wRref(F2) = 0.0992, T = 293(2) K.

Field‐Induced SMM and Visible/NIR‐Luminescence Behaviour of Dinuclear LnIII Complexes with 2‐Fluorobenzoate

“…In this work, we present the structure of six new dinuclear 4f‐metal complexes by simultaneously using bidentate bridging carboxylate groups derived from 2‐fluorobenzoic acid (H‐2‐FBz), chelating 1,10‐phenanthroline (phen) and nitrato capping ligands. Four of the new reported compounds have the formula [Ln 2 (2‐FBz) 4 (NO 3 ) 2 (phen) 2 ] {Ln = Nd ( 1 ), Eu ( 2 ), Ln = Gd ( 3 ), Ln = Dy ( 5 ), Ln = Er ( 6 )} and are isostructural to the previously reported [Tb 2 (2‐FBz) 4 (NO 3 ) 2 (phen) 2 ] ( 4 ) compound. The coordination number of the lanthanide ions is 9 for 1 – 6 .…”

“…To avoid the highly energetic and not very controllable hydro‐ or solvothermal processes, in this work, we used a straightforward room‐temperature synthetic procedure, different from that used to prepare the already published complex [Tb 2 (2‐FBz) 4 (NO 3 ) 2 (phen) 2 ], and have successfully obtained the latter and six new dinuclear lanthanide compounds. Five of the mentioned complexes are isostructural with the Tb III one, but when using Yb III as the lanthanide source, the complex obtained is different and has the formula [Yb 2 (2‐FBz) 6 (phen) 2 ].…”