Crystal structure of bis(μ₂-ferrocenecarboxylato-κ² O:O′)-bis(1,10-phenanthroline-κ² N,N′)-(μ₂-methanolato-κ² O,O)dicopper(II) tetrafluoroborate – acetonitrile (1/1), C₄₉H₄₀BCu₂F₄Fe₂N₅O₅

Abstract

C49H40BCu2F4Fe2N5O5, triclinic, P1̄ (no. 2), a = 11.526(2) Å, b = 12.902(2) Å, c = 15.469(3) Å, α = 95.632(2)°, β =107.789(2)°, γ = 96.251(2)°, V = 2156.3(7) Å3, Z = 2, Rgt(F) = 0.0443, wRref(F2) = 0.1198, T = 100(2) K.

Crystal structure of di(naphthalen-2-yl)sulfane, C20H14S

“…This chromophore could be modified on the surface of coinage metal clusters for dual emission character [6] or stabilizing the cluster core via intra-cluster interactions [7]. In order to fix the naphthalene group on the surface of copper clusters for functional coinage complex [8][9][10][11][12], we try to mix 2-naphthalenethiol and bipyridine (auxiliary ligand) with CuI under the solvothermal conditions. The title compound, was obtained as the by-product from the coordination reaction, which was an unexpected product here from the Williamson ether synthesis [13] via CuI as catalyst.…”