Crystal structure of catena-poly[aqua-(methanol-κO)-bis(μ₂-4-(pyridin-4-yl)benzoato-κ² N:O)-bis(triphenylphospine-κP)disilver(I)], C₆₁H₅₂Ag₂N₂O₆P₂

Abstract

CCDC no.: 890651A part of the title crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters. Source of materialThe title compound was obtained by the reaction of silver(I) sulfate (0.0624 g, 0.2 mmol) and triphenylphosphine (PPh 3 ) (0.0525 g, 0.2 mmol) in the presence of 4-pyridin-4-yl-benzoic acid (0.0398 g, 0.2 mmol) in the mixed solution of CH 3 OH (5 mL) and CH 2 Cl 2 (5 mL) for 6 h at ambient temperature. The insoluble residues were removed by filtration, and the filtrate was evaporated slowly at room temperature for about 1 week to yield transparent and colorless crystals. Crystals suitable for single-crystal X-ray diffraction were selected directly from the sample as prepared. Experimental detailsMulti-scan absorption corrections were applied using SADABS program. All the structures were solved by direct methods using SHELXS program of the SHELX-2014/6 package and refined with SHELXL-2014/6 [2]. The final