Crystal structure of catena-poly[aqua-(μ₃-1,3,5-benzenetricarboxylato-κ³ O:O′:O′′)-[μ₃hydroxy-(1,3-di-(μ₂-1,2,4-triazole-4-yl)benzoato-κ² N:N′)copper(II)], C₁₉H₁₆Cu₂N₆O₉

Abstract

CCDC no.: 1555012The crystal structure is shown in the figure. Tables 1 and 2 contain details on crystal structure and measurement conditions and a list of the atoms including atomic coordinates and displacement parameters. Source of materialThe title compound was prepared by hydrothermal method. A mixture of Cu(OAc) 2 ·4H 2 O (0.038 g, 0.2 mmol), 1,3,5-benzenetricarboxylic acid (0.021 mg, 0.1 mmol), 3,5-di(1,2,4-triazole-4)benzenecarboxylic acid (0.0256 g, 0.1 mmol), and H 2 O (10 mL) was sealed in a 25 mL Teflon-lined stainless steel vessel and heated at 140°C for 3 days. The reaction mixture was slowly cooled to room temperature at a rate of 3°C/h, and the blue block crystals were collected, washed with water and dried in air.