Crystal structure ofcatena-poly[[bis(N-acethylthiomorpholine-κS)copper(I)]-μ-iodido]

Abstract

In the title compound, the CuI atom is coordinated by two S atoms and two I atoms in a distorted tetra­hedral mode.

Influence of C–H/X (X = S, Cl, N, Pt/Pd) Interactions on the Molecular and Crystal Structures of Pt(II) and Pd(II) Complexes with Thiomorpholine-4-carbonitrile: Crystallographic, Thermal, and DFT Study

“… The coordination modes of N- TMLs observed in the crystal structures of the complexes are monodentate coordination via the S atom, mixed N,S chelation, and coordination of the N atom together with other donor atoms from the R substituent. Exclusive coordination via the sulfur atom was observed in the case of polymeric Cu complexes where ligands contain electron-withdrawing amide groups bonded to N -TMLs. − A typical, exclusive axial conformer was observed only in the case of two Cu­(I) coordination polymers. , It is worth mentioning that, in the mixed N,S bidentate chelates, N -TMs coordinate in the higher energy boat conformation. There have been several reports on the possible application of metal complexes with N -TMs.…”