Abstract:The molecular and crystal structures of the title complex, [Ru(C10H8N2)(C12H9NO)(C2H6OS)2](CF3O3S)2 or cis(S),trans(O,N
bpy)-[Ru(bpy)(ppk)(dmso-S)2](OTf)2 {bpy = 2,2′-bipyridine, ppk = phenyl-2-pyridyl ketone [IUPAC nomenclature: phenyl(pyridine-2-yl)methanone], dmso = dimethyl sulfoxide, and OTf− = trifluoromethanesulfonate}, are reported. The Ru2+ ion has a distorted octahedral geometry with two bpy N atoms, the N and O atoms of ppk, and two S atoms of two cis dmso-S ligands. The carbonyl O… Show more
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