Crystal structure of monocarbonyl(N-nitroso-N-oxido-phenylamine-κ² O,O′)(triphenylarsine-κAs)rhodium(I), C₂₅H₂₀AsN₂O₃Rh

Abstract

CCDC no.: 1447254The crystal structure is shown in the gure. Tables 1-3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Source of materialThe title compound was prepared by dissolving rhodium dicarbonyl cupferrate (N-nitroso-N-oxido-phenylamine) (0.1 g, 0.34 mmol) [1] in 2 mL acetone and ltering over Celite, which was rinsed with another 2 mL acetone. Triphenylarsine (0.109 g 1.05 mmol) was dissolved in 2 mL acetone and added dropwise to the rhodium cupferate, during which the solution