Crystal structure of N,N,N',N',N'',N''-hexakis(2-methylallyl)-[1,3,5]- triazin-2,4,6-triamine, C27H42N6

Ricken, S.; Koç, F.; Schürmann, M.; Preut, H.; Eilbracht, P.

doi:10.1524/ncrs.2006.0153

Cited by 2 publications

(2 citation statements)

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“…In the crystal structure of A3M, the distance between the hydrogen H5 and the nitrogen N4 was 2.298 Å and the C5–H5–N4 bond angle was 120°, in agreement with the expected chemical structure (Figure a). These selected bond lengths and angles were consistent with the reported values in literature. − The crystal structure refinement parameters are summarized in Tables S1–S14.…”

Section: Resultssupporting

confidence: 83%

Synthesis of Multifunctional Charge-Transfer Agents: Toward Single-Walled Carbon Nanotubes with Defined Covalent Functionality and Preserved π System

et al. 2021

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The attachment of well-defined charge-transfer agents to the surface of nanomaterials is an efficient strategy to control their charge density and also to tune their optical, electrical, and physicochemical properties. Particularly interesting are charge-transfer agents that either donate or withdraw electrons depending on the arrangements of their building units and that promise a nondestructive attachment to delicate nanomaterials like sp2 compounds. In this work, we rationally synthesize molecular moieties with versatile functionalities. A reactive anchor group allows us to attach them to carbon nanotubes as defined charge-transfer agents while preserving the tubes’ π-conjugation. The charge-transfer agents were synthesized through the stepwise nucleophilic substitution of either one (monosubstituted series) or two (disubstituted series) chlorine atoms of cyanuric chloride by aniline derivatives containing one, two, or three methoxy groups in the para and meta positions. Variation in the number and position of the methoxy group as an electron-transferring group helps us to manipulate the electronic and optical properties of the molecular probes and their charge transfer to the single-walled carbon nanotubes (SWNTs) systematically. The correlation between the optical properties of these molecular probes and their functionality was investigated by experiments and quantum chemical calculations. While the optoelectronic properties of the conjugated charge-transfer agents were dominated by the aniline segments, the triazine warrants the ability to nondestructively attach to the surface of SWNTs. This study is one step ahead toward the production of SWNTs with desired optical and electrical properties by covalent π-preserving functionalization.

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Section: Resultssupporting

confidence: 83%

Synthesis of Multifunctional Charge-Transfer Agents: Toward Single-Walled Carbon Nanotubes with Defined Covalent Functionality and Preserved π System

et al. 2021

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“…Interestingly, kdr mutations cluster in particular channel regions, such as the linker between S4 and S5 (L45) and S5 of DI, L45, S5 and S6 of DII, and S6 of DIII, suggesting Na v 1 may possess discrete pyrethroid binding sites. Potential Na v 1‐ligand interactions were assessed through the construction of homology models of insect Na v 1 based on available crystal structures of bacterial sodium and mammalian potassium channels . This approach led to the prediction of two pyrethroid binding sites, one of which involves L45 and S5 of DII and S6 of DIII, while the second site is composed of L45 and S5 of DI and S6 of DII …”

Section: Discussionmentioning

confidence: 99%

Mutations in voltage‐gated sodium channels from pyrethroid resistant salmon lice (Lepeophtheirus salmonis)

Carmona‐Antoñanzas

Helgesen

Humble

et al. 2018

Pest Management Science

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Crystal structure of N,N,N',N',N'',N''-hexakis(2-methylallyl)-[1,3,5]- triazin-2,4,6-triamine, C27H42N6

Cited by 2 publications

References 1 publication

Synthesis of Multifunctional Charge-Transfer Agents: Toward Single-Walled Carbon Nanotubes with Defined Covalent Functionality and Preserved π System

Synthesis of Multifunctional Charge-Transfer Agents: Toward Single-Walled Carbon Nanotubes with Defined Covalent Functionality and Preserved π System

Mutations in voltage‐gated sodium channels from pyrethroid resistant salmon lice (Lepeophtheirus salmonis)

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