Crystal structure, optical characterization, conduction and relaxation mechanisms of a new hybrid compound (C6H9N2)2[Sb2Cl8]

Chaabane, I.; Rekik, W.; Ghalla, H.; Zaghrioui, M.; Lhoste, J.; Oueslati, A.

doi:10.1039/d3ra08885e

RSC Adv.

2024

DOI: 10.1039/d3ra08885e

|View full text |Cite

Crystal structure, optical characterization, conduction and relaxation mechanisms of a new hybrid compound (C₆H₉N₂)₂[Sb₂Cl₈]

I. Chaabane,

W. Rekik,

H. Ghalla

et al.

Abstract: Hybrid materials play a crucial role in the construction of flexible electronic devices due to the advantages of both organic and inorganic components.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 70 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Synthesis, crystal structure, and ionic conductivity of a new organic–inorganic bromides (C6H9N2)2[SbBr4]Br

Chaabane,

Rekik,

Zaghrioui

et al. 2024

Ionics

View full text Add to dashboard Cite

Synthesis, crystal structure, and ionic conductivity of a new organic–inorganic bromides (C6H9N2)2[SbBr4]Br

Chaabane,

Rekik,

Zaghrioui

et al. 2024

Ionics

View full text Add to dashboard Cite

A 0D Ge(II)-Halide-Based Perovskite with Enhanced Semiconducting Behavior for Electronic Capacitors

Ben Messaoud,

Abid,

Elleuch

et al. 2024

ACS Omega

View full text Add to dashboard Cite

Perovskite materials have surged to the forefront of materials science, captivating researchers worldwide with their distinctive crystal lattice arrangement and remarkable optical, electric and dielectric attributes. The current study focuses on the development of a novel zero-dimensional (0D) Ge(II)-based hybrid perovskite, formulated as NH3(CH2)2NH3GeF6, and synthesized through a gradual evaporation process conducted at room temperature. The crystal structure is characterized by an arrangement of organic cations and isolated octahedral [GeF6]2– groups. This configuration is stabilized by relatively weak intermolecular bonds. A comprehensive analysis of the material’s thermal properties using differential scanning calorimetry (DSC) revealed a distinct phase transition occurring at approximately 323 K, which was further confirmed through electrical measurements. The studied compound provided a broad absorption range across the visible spectrum and an optical band gap of 3.30 eV, indicating its potential for semiconducting applications in optoelectronic devices. Photoluminescence PL analysis displays a blueish broad-band emission with a high color rendering index CRI value of 91, when excited at 325 nm. This emission primarily originates from the self-trapped excitons (STEs) recombination in the inorganic [GeF6]2−. Herein, the temperature-dependent behavior of grain conductivity exhibited an Arrhenius-type pattern, with an activation energy (E a) of 0.46 eV, confirming the semiconductor nature of the investigated compound. In addition, a deep investigation of the alternating current conductivity, analyzed using Jonscher’s law, demonstrates that the conduction mechanism is effectively described by the correlated barrier hopping (CBH) model. The dielectric performances show a significant dielectric constant (ε′ ∼ 103). Thus, all these interesting physical properties of this hybrid perovskite have paved the way for advancements in various technological applications, particularly in the field of electronic capacitors.

show abstract

Crystal structure, Hirshfeld surface analysis, conduction mechanism and electrical modulus study of the new organic–inorganic compound [C₈H₁₀NO]₂HgBr₄

Chkoundali,

Garoui,

Trigui

et al. 2024

RSC Adv.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Crystal structure, optical characterization, conduction and relaxation mechanisms of a new hybrid compound (C₆H₉N₂)₂[Sb₂Cl₈]

Abstract: Hybrid materials play a crucial role in the construction of flexible electronic devices due to the advantages of both organic and inorganic components.

Cited by 3 publications

References 70 publications

Synthesis, crystal structure, and ionic conductivity of a new organic–inorganic bromides (C6H9N2)2[SbBr4]Br

Synthesis, crystal structure, and ionic conductivity of a new organic–inorganic bromides (C6H9N2)2[SbBr4]Br

A 0D Ge(II)-Halide-Based Perovskite with Enhanced Semiconducting Behavior for Electronic Capacitors

Crystal structure, Hirshfeld surface analysis, conduction mechanism and electrical modulus study of the new organic–inorganic compound [C₈H₁₀NO]₂HgBr₄

Contact Info

Product

Resources

About

Crystal structure, optical characterization, conduction and relaxation mechanisms of a new hybrid compound (C6H9N2)2[Sb2Cl8]

Abstract: Hybrid materials play a crucial role in the construction of flexible electronic devices due to the advantages of both organic and inorganic components.

Cited by 3 publications

References 70 publications

Synthesis, crystal structure, and ionic conductivity of a new organic–inorganic bromides (C6H9N2)2[SbBr4]Br

Synthesis, crystal structure, and ionic conductivity of a new organic–inorganic bromides (C6H9N2)2[SbBr4]Br

A 0D Ge(II)-Halide-Based Perovskite with Enhanced Semiconducting Behavior for Electronic Capacitors

Crystal structure, Hirshfeld surface analysis, conduction mechanism and electrical modulus study of the new organic–inorganic compound [C8H10NO]2HgBr4

Contact Info

Product

Resources

About

Crystal structure, optical characterization, conduction and relaxation mechanisms of a new hybrid compound (C₆H₉N₂)₂[Sb₂Cl₈]

Crystal structure, Hirshfeld surface analysis, conduction mechanism and electrical modulus study of the new organic–inorganic compound [C₈H₁₀NO]₂HgBr₄