Crystal structure, thermochromic and magnetic properties of organic-inorganic hybrid compound: (C 7 H 7 N 2 S) 2 CuCl 4

Vishwakarma, Ashok K.; Kumari, Reema; Ghalsasi, Prasanna S.; Arulsamy, Navamoney

doi:10.1016/j.molstruc.2017.03.076

Cited by 13 publications

(3 citation statements)

References 30 publications

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“…In the half cation the C-C/C-N bonds are almost equivalent: C2-C3 = 1.3867 (2) Å; C3-C4 = 1.3929 (2) Å and C2-N1 = 1.4607 (2) Å. The C-C-C and C-C-N angles vary within the range from 119.40 (1)˚ and 119.815 (1), respectively. The main inter atomic distances and angles in the cation are reported in Table 2.…”

Section: Xrd Descriptionmentioning

confidence: 96%

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Effect of Changing Anion on the Crystalline Structure, Crystal Structure, Hirschfield Surface, IR and NMR Spectroscopy of Organic Salts and Hybrid Compounds: C6H4(NH3)2Cl2 (I), β-[C6H10N<sub&g

Hannachi¹,

Elwej²,

Roisnel³

et al. 2023

OJIC

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Two organic-inorganic hybrid materials, C 6 H 4 (NH 3 ) 2 •Cl 2 (I) and β-[C 6 H 10 N 2 ] 2 ZnCl 4 (II), have been synthesized by hydrothermal method. These two materials are one of the hybrid materials have emerged as one of the most brilliant components classes. These extraordinary compounds synergistically combine the desired physical properties of both organic and inorganic components into a single compound offering the possibility to achieve great improvement over time in terms of science across various sectors. Their structures were determined by XRD pattern investigations and single crystal X-ray diffraction. These two compounds are crystallized in the monoclinic system; C2/c space group. In the both structures, the anionic-cationic entities are interconnected by hydrogen bonding contacts and p-p Interaction forming threedimensional networks. Intermolecular interactions were investigated by Hirshfeld surfaces and the contacts of the four different chloride atoms in (II) were compared. The vibrational absorption bands were identified by infrared spectroscopy. These compounds were also investigated by solid state 13 C NMR spectroscopy.

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Section: Xrd Descriptionmentioning

confidence: 96%

“…Organic-inorganic metal halides have captivated vigorous concern in the last decades due to both technological features as well as potential applications in several physical properties [1] [2] [3] [4].…”

Section: Introductionmentioning

confidence: 99%

Effect of Changing Anion on the Crystalline Structure, Crystal Structure, Hirschfield Surface, IR and NMR Spectroscopy of Organic Salts and Hybrid Compounds: C6H4(NH3)2Cl2 (I), β-[C6H10N<sub&g

Hannachi¹,

Elwej²,

Roisnel³

et al. 2023

OJIC

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“…Up to date, hybrid solids are subject to many scientific studies due to their low cost, ease of synthesis, structural tenability and specific physical, chemical and biological properties. Such materials can be applied in both academic research and technological applications such as optic [8,9], electronic [10], mechanics, sensors, magnetism [11,12], catalysis and medicine [13,14].…”

Section: Introductionmentioning

confidence: 99%

Growth, crystal structure, Hirshfeld surface analysis, DFT studies, physicochemical characterization, and cytotoxicity assays of novel organic triphosphate

et al. 2022

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A novel interesting organic-inorganic hybrid compound, named (1-phenylpiperazinium) trihydrogen triphosphate, with the formula (C 10 H 15 N 2 ) 2 H 3 P 3 O 10 has been obtained by low speed of evaporation at room temperature after using the ion exchange chemical procedure. To carry out a detailed crystallographic structure analysis, single-crystal X-ray diffraction has been reported. In the molecular arrangement, the different entities are held together through N-H … O, O-H … O and C-H … O hydrogen bonds, building up a three dimensional packing. Powder X-ray diffraction analysis is acquired to confirm the purity of the product. The nature and the proportion of intermolecular interactions were investigated by Hirshfeld surfaces analysis. In order to support the experimental results, a density functional theory (DFT) calculation were performed, using the Becke-3-Parameter-Lee-Yang-Parr (B3LYP) function with LANL2DZ basis set, and the data indicate the much agreement between the experimental and the theoretical results. Thus, the physicochemical properties were studied employing a variety of techniques (FT-IR, NMR, UV-Visible and photoluminescence). To get an insight of the possible employment of the present material in biology, cell viability assays were performed.

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Synthesis, Crystal Structure, Hirshfeld Surface Analysis, Molecular Docking, IR Spectroscopy and DFT Calculations of a Novel 2D Layered Hybrid Compound (C6H10N3O)2Cu2Cl6

et al. 2022

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Crystal structure, thermochromic and magnetic properties of organic-inorganic hybrid compound: (C 7 H 7 N 2 S) 2 CuCl 4

Cited by 13 publications

References 30 publications

Effect of Changing Anion on the Crystalline Structure, Crystal Structure, Hirschfield Surface, IR and NMR Spectroscopy of Organic Salts and Hybrid Compounds: C<sub>6</sub>H<sub>4</sub>(NH<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub> (I), <i>β</i>-[C<sub>6</sub>H<sub>10</sub>N<sub&g

Effect of Changing Anion on the Crystalline Structure, Crystal Structure, Hirschfield Surface, IR and NMR Spectroscopy of Organic Salts and Hybrid Compounds: C<sub>6</sub>H<sub>4</sub>(NH<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub> (I), <i>β</i>-[C<sub>6</sub>H<sub>10</sub>N<sub&g

Growth, crystal structure, Hirshfeld surface analysis, DFT studies, physicochemical characterization, and cytotoxicity assays of novel organic triphosphate

Synthesis, Crystal Structure, Hirshfeld Surface Analysis, Molecular Docking, IR Spectroscopy and DFT Calculations of a Novel 2D Layered Hybrid Compound (C6H10N3O)2Cu2Cl6

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