Crystal structure, vibrational spectra and DFT studies of hydrogen bonded 1,2,4–triazolium hydrogenselenate

Arjunan, V.; Thirunarayanan, S.; Marchewka, M.K.; Mohan, S.

doi:10.1016/j.molstruc.2017.05.107

Cited by 6 publications

(1 citation statement)

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“…The spectrum of 1 exhibits an additional ν (C=N) band with medium intensity at 1566 cm −1 . which is attributed to triazolium cations . These moieties give rise to an intense ν (C−H) absorption at 3135 cm −1 , whereas the shoulder on this band at about 3127 cm −1 is assigned to the ν (C−H) mode for coordinated 1,2,4‐triazole.…”

Section: Resultsmentioning

confidence: 99%

A Linear Trinuclear Oxidodiperoxido‐molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions

et al. 2018

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The complex (Htrz)2[Mo3O6(O2)4(trz)2]⋅H2O (1), isolated from the reaction of MoO3 with H2O2 in the presence of 1,2,4‐triazole (trz), displays singular structural features such as double bridges comprising one oxido and one triazole ligand, and peripheral oxidodiperoxido‐molybdenum(VI) units. A comparative study was performed regarding the catalytic activity and stability of complex 1 and the hybrid material [MoO3(trz)0.5] (2) for the epoxidation of cis‐cyclooctene (Cy8), the alcoholysis of epoxides, and the acetalization of benzaldehyde (PhCHO). Methanol or ethanol were used as solvents and reagents for the latter two reactions. For the substrates Cy8, styrene oxide, and PhCHO, the corresponding epoxide, β‐alkoxy alcohol, and dialkyl acetal were obtained with 100 % selectivity at very high conversions. In general, 1 performed better than 2 for the different catalytic reactions. Under certain oxidant/co‐solvent conditions used for Cy8 epoxidation, 1 was converted to 2 during the reaction.

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Section: Resultsmentioning

confidence: 99%