Crystal structures of three lead(II) acetate-bridged diaminobenzene coordination polymers

Abstract

The structures of three lead(II) coordination polymers are reported. One exhibits a two-dimensional structure, whereas the other two are one-dimensional. All three exhibit bidentate bridging acetate and monodentate benzene-1,2-di­amine ligands. The extended structures reveal extensive hydrogen-bonding networks involving the di­amine and acetate ligands.

Charge-assisted hydrogen bonding in three diaminobenzene salts

“…ortho, meta, and para substitution) (Dobrzycki & Woźniak, 2008) and the ability to engage inand C-HÁ Á Á interactions, in addition to more traditional hydrogen bonding (Deng et al, 2012). We have taken advantage of these attributes to synthesize coordination polymers containing benzenediamine ligands (Geiger et al, 2016;Geiger, Parsons & Zick, 2014;.…”

Quantum Dynamics Simulations on the Adsorption Mechanism of Reducing and Oxidizing Gases on the CH3NH3PbI3 Surface

“…The average lengths of Pb1–N35, Pb1–N15, Pb7–N16, Pb5–N8, and Pb7–N12 bonds after realizing a stable connection in the simulation process were 2.554, 2.623, 2.514, 2.572, and 2.586 Å, respectively, which were lower than the known length (2.91 Å) of Pb–N coordinate bond. [ 44 ] This further verified that both NH 3 molecules and the CH 3 NH 2 groups could attack the Pb–I skeleton and strongly interacted with Pb atoms. Moreover, the interaction persisted.…”

Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures

“…Metal-organic frameworks (MOFs) have received much attention because of their many potential applications including gas storage, catalysis, chemical sensors and molecular separation (Dey et al, 2014;Kreno et al, 2012;Farha & Hupp, 2010). Our previous efforts in the area of coordination polymers have focused on compounds based on phenylenediamine and acetate ligands incorporating Zn II (Geiger & Parsons, 2014) and Pb II (Geiger et al, 2014). We have extended this work to include Cd and report the structural analyses of two Cd compounds herein.…”

“…Both acetato-2 O,O 0 and 2 -acetato-2 O:O 0 modes are found in (II). Numerous examples of structures with benzene-1,2-diamines exhibiting monodentate and/or bidentate coordination modes have been reported (Narayanan & Bhadbhade, 1996;Ovalle-Marroquín et al, 2002;Ariyananda & Norman, 2005;Chen et al, 2006;Maxcy et al, 2000;Qian et al, 2007;Dickman, 2000;Mei et al, 2009;Djebli et al, 2012;Zick & Geiger, 2016;Geiger et al, 2014;Geiger & Parsons, 2014;Geiger, 2012). Examples of benzene-1,4-diamine metal-complex structures ISSN 2056-9890 have also been reported (Batten et al, 2001;Faizi & Prisyazhnaya, 2015).…”