Crystal-to-crystal polymerisation of monosubstituted [PW11O39Cu(H2O)]5− Keggin-type anions

Ruiz-Bilbao, Estibaliz; Pache, Aroa; Barrenechea, Unai; Reinoso, Santiago; San Felices, Leire; Vivanco, Maria dM.; Lezama, Luis; Artetxe, Beñat; Gutiérrez-Zorrilla, Juan M.

doi:10.1039/d4dt00690a

Dalton Trans.

2024

DOI: 10.1039/d4dt00690a

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Crystal-to-crystal polymerisation of monosubstituted [PW₁₁O₃₉Cu(H₂O)]⁵⁻ Keggin-type anions

Estibaliz Ruiz-Bilbao,

Aroa Pache,

Unai Barrenechea

et al.

Abstract: Compound [C(NH2)3]10[{PW11O39Cu(H2O)}2{Cu(pic)2}]·10H2O (1, pic = picolinate) undergoes a thermally-triggered single-crystal-to-single-crystal transformation that involves an unprecedented solid-state polymerisation of monosubstituted Keggin anions.

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Syntheses and Color-Changing Properties of Three PW₁₁M (M = Ni, Cu, and Zn)-Based Viologen Compounds

Hao,

Liu,

Ying

et al. 2024

Crystal Growth & Design

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Three POM−viologen compounds were synthesized at a temperature of 120 °C by a traditional hydrothermal technique, namely-bis(cyclopropylmethyl)-4,4′-bipyridine bromide). All three compounds contain PW 11 M (M = Ni, Cu, and Zn), a transition metal Msubstituted monosubstituted Keggin-type structure. These three compounds can exhibit a variety of excellent properties to stimulate discoloration in light, heat, and electricity. Moreover, PW 11 Cu-BCby and PW 11 Zn-Cby can be applied to inkless erasable printing and dual anticounterfeiting applications based on their photochromic behaviors.

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Syntheses and Color-Changing Properties of Three PW₁₁M (M = Ni, Cu, and Zn)-Based Viologen Compounds

Hao,

Liu,

Ying

et al. 2024

Crystal Growth & Design

View full text Add to dashboard Cite

show abstract

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Crystal-to-crystal polymerisation of monosubstituted [PW₁₁O₃₉Cu(H₂O)]⁵⁻ Keggin-type anions

Abstract: Compound [C(NH2)3]10[{PW11O39Cu(H2O)}2{Cu(pic)2}]·10H2O (1, pic = picolinate) undergoes a thermally-triggered single-crystal-to-single-crystal transformation that involves an unprecedented solid-state polymerisation of monosubstituted Keggin anions.

Cited by 1 publication

References 51 publications

Syntheses and Color-Changing Properties of Three PW₁₁M (M = Ni, Cu, and Zn)-Based Viologen Compounds

Syntheses and Color-Changing Properties of Three PW₁₁M (M = Ni, Cu, and Zn)-Based Viologen Compounds

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Crystal-to-crystal polymerisation of monosubstituted [PW11O39Cu(H2O)]5− Keggin-type anions

Abstract: Compound [C(NH2)3]10[{PW11O39Cu(H2O)}2{Cu(pic)2}]·10H2O (1, pic = picolinate) undergoes a thermally-triggered single-crystal-to-single-crystal transformation that involves an unprecedented solid-state polymerisation of monosubstituted Keggin anions.

Cited by 1 publication

References 51 publications

Syntheses and Color-Changing Properties of Three PW11M (M = Ni, Cu, and Zn)-Based Viologen Compounds

Syntheses and Color-Changing Properties of Three PW11M (M = Ni, Cu, and Zn)-Based Viologen Compounds

Contact Info

Product

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Crystal-to-crystal polymerisation of monosubstituted [PW₁₁O₃₉Cu(H₂O)]⁵⁻ Keggin-type anions

Syntheses and Color-Changing Properties of Three PW₁₁M (M = Ni, Cu, and Zn)-Based Viologen Compounds

Syntheses and Color-Changing Properties of Three PW₁₁M (M = Ni, Cu, and Zn)-Based Viologen Compounds