Non-doped and 0.1, 0.5, 1.0, and 2.0% Ce-doped (Gd 0.4 Lu 0.6 ) 8 Sr 2 (SiO 4 ) 6 O 2 crystals were prepared and their optical and scintillation properties were investigated. Their X-ray diffraction (XRD) patterns confirmed that the Ce-doped samples did not contain an impurity phase, whereas the non-doped one contained some impurity phases such as Gd 2 SiO 5 and Lu 2 SiO 5 . The emission due to 5d-4f transitions of Ce 3+ was observed at 380-650 nm in both the photoluminescence (PL) and scintillation spectra of the Ce-doped samples. The scintillation light yields (LYs) of the 0.5 and 1.0% Ce-doped samples under 241 Am α-ray irradiation were ~230 and ~620 ph/5.5 MeV-α, respectively.