Crystallisation and zircon saturation of calc-alkaline tonalite from the Adamello Batholith at upper crustal conditions: an experimental study

Abstract

The understanding of the geochemical and petrophysical evolution of magmas forming intermediate calc-alkaline batholiths at shallow crustal levels critically depends on knowledge of the phase equilibria relations along the liquid line of descent.Here, we present experimental results for a tonalitic system at a pressure of 200 MPa and under water-saturated conditions. Melting experiments were performed at temperatures between 700 and 1000 °C in externally heated HCM pressure vessels, with oxygen fugacity controlled close to the Ni-NiO buffer equilibrium (NNO) employing an argon-methane mixture as pressure medium and Co-Pd redox sensors to verify fO 2 conditions. Natural rock powder of a medium-K tonalite from the Adamello Batholith in Northern Italy served as experimental starting material. Based on compositional data of stable phases in the run products and images of entire run charges, mass balance calculations as well as image processing were performed to investigate the evolution of the crystal/melt ratio with respect to temperature. Furthermore, compositional trends of minerals as well as the liquid line of descent of residual melts were obtained. Orthopyroxene, clinopyroxene and plagioclase were identified as near-liquidus phases (below 990 °C). At 900 °C, amphibole joins the solid-phase assemblage at the expense of clinopyroxene, indicating the existence of a peritectic relationship. After an initial near-linear decrease with temperature, residual melt fractions exhibit a plateau of 45-55 vol. % between 750 and 850 °C, followed by a rapid decrease coinciding with quartz saturation at 725 °C. Compositions of residual liquids evolve along a typical calc-alkaline differentiation trend with decreasing temperature (increasing SiO 2 and decreasing TiO 2 , Al 2 O 3 , CaO, MgO and FeO contents) and become peraluminous below 900 °C. Intermediate to acidic rocks from the Adamello follow the experimental liquid line of descent indicating that the observed compositional spread of the natural intermediate composition rock record can be explained by low-pressure magma differentiation and liquid extraction. Experimentally determined zircon saturation levels are at low temperatures distinctly lower compared to existing and often used Zr-saturation models, but fully consistent with observed and modelled Zr-evolution trends from the natural rock record of the Southern Adamello Batholith inferring that zircon saturation in these intermediate to felsic plutonic rocks occurred at 800-830 °C corresponding to a melt fraction of about 50 vol. %.

A connection between magma chamber processes and eruptive styles revealed at Nisyros-Yali volcano (Greece)

“…The storage temperatures of ~780 °C that we obtain from amphibole-plagioclase pairs for the Post-caldera domes (details in the next section) are in agreement with the presence of quartz and accessory biotite, which require storage temperatures of <800 °C (e.g. Rutherford and Devine, 2003;Marxer and Ulmer, 2019).…”

Determining the current size and state of subvolcanic magma reservoirs

“…8). The time evolution of the volume fraction of melt with temperature >812°C, equivalent to magma with < 50% crystallinity 45 , which is corresponding to the typical rheological transition from the non-eruptible to eruptible state of silicic magmas 11 , is shown for a numerical simulation that matches the natural data in Fig. 8a.…”

“…Considering that zircon from Nevado de Toluca records continuous melt presence in the plumbing system for at least 900 ka, this temperature distribution suggests that magma is primarily stored in a highly crystallized state for most of this time in an upper crustal plumbing system. For example, equilibrium crystallization of andesitic liquids indicates a crystallinity of 67 vol.% for a temperature of 725°C 45 . Given typical whole rock Zr contents of 140 µg/g for Nevado de Toluca 39,44 , which are in good agreement with most intermediate to silicic calc-alkaline magmas, Zr saturation temperatures <825°C can be expected 45 .…”

“…For example, equilibrium crystallization of andesitic liquids indicates a crystallinity of 67 vol.% for a temperature of 725°C 45 . Given typical whole rock Zr contents of 140 µg/g for Nevado de Toluca 39,44 , which are in good agreement with most intermediate to silicic calc-alkaline magmas, Zr saturation temperatures <825°C can be expected 45 . Typical eruptive temperatures of 820-960°C for andesite and dacites from Nevado de Toluca 38,44 are close to, but generally in excess of zircon saturation, suggesting that the eruptive products are mixtures of hot recharge pulses and remobilized crystal-rich magmas.…”

Supplemental Material: Modulation of zircon solubility by crystal–melt dynamics

“…Wolff et al (2000) and Edgar et al (2002) screened for mixing, alkali loss and cumulate melting (high Ba). 'Adamello' data are compositions of melt in 0.7 GPa fractional crystallization experiments of Nandedkar et al (2014) with starting materials equivalent to primitive Adamello batholith compositions; Zr contents are modeled using the equilibrium crystallization equation and parametrizations of Zr-melt partition coefficients from Marxer and Ulmer (2019).…”