Crystallization and electrochemical corrosion behaviors of nanometer amorphous Ni-P alloys

Abstract

Ni-P alloy coatings with a phosphorus content of 11.65 wt% were deposited by electroless plating. The as-plated nano-amorphous Ni-P alloy coatings were heated in air for 1 h at 200-500°C. By using an atomic force microscope and the x-ray diffraction method, the nanocrystalline morphology and the crystallization phase identification of the coatings were studied. The corrosion behavior of the coatings in the 3.5 wt% NaCl solution was analyzed using polarization curves and impedance spectroscopy. It was observed that the corrosion behavior of the coatings was affected by the change in the nanocrystalline structure; during the heat treatment, the nanocrystalline structure of the coating alloy undergoes sequential changes from amorphous→the adjustment of amorphous→precipitated phase→crystalline. Meanwhile, the corrosion behavior of the coating alloy has also changed from uniform corrosion controlled by charge transfer→uniform corrosion controlled by diffusion→ grain boundary corrosion. The Ni phase and the Ni 3 P phase developed a compact and dense nanocrystal layer on the surface of the coating alloy, in which the best performance by the corrosion resistant coating can be found.