2003
DOI: 10.1016/s0032-3861(02)00762-0
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Crystallization kinetics and solidified structure in iPP under high cooling rates

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Cited by 119 publications
(119 citation statements)
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“…At a depth of 20 μm in actual specimens, non-NAPP showed α-form crystals and β-specific NA promoted α-form crystals instead of the β-form. Previous studies have suggested that the mesomorphic form prevails over the α-form above approximately 80 °C/s [10], and the crystal growth rate of α-form is faster than that of the β-form crystal when the temperature is lower than 90 °C [22]. The supercooled melt crystallizes after the temperature decreases.…”
Section: Crystallization Near the Surface In Injection Moldingmentioning
confidence: 93%
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“…At a depth of 20 μm in actual specimens, non-NAPP showed α-form crystals and β-specific NA promoted α-form crystals instead of the β-form. Previous studies have suggested that the mesomorphic form prevails over the α-form above approximately 80 °C/s [10], and the crystal growth rate of α-form is faster than that of the β-form crystal when the temperature is lower than 90 °C [22]. The supercooled melt crystallizes after the temperature decreases.…”
Section: Crystallization Near the Surface In Injection Moldingmentioning
confidence: 93%
“…The mesomorphic-form crystal is expected due to the high cooling rates at the surface [10]. The relaxation process of stretched polymer chains takes place below the surface.…”
Section: Crystallization Near the Surface In Injection Moldingmentioning
confidence: 99%
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“…The polypropylene (i-PP) grade adopted in this study was supplied by Montell (now Basell), and its commercial name is T30G (non-nucleated, Mw=376 000, Mw/Mn=6.7, tacticity=87.6%): it was extensively characterized as far as rheology and crystallization kinetics [7][8][9][10].…”
Section: Methodsmentioning
confidence: 99%