Crystallization kinetics of poly(1,4-butylene-co-ethylene terephthalate)

Chou, R.; Chang, Chi-Chin; Yu, T. Leon; Tseng, Yao-Hsuan; Wu, Mo-Jyi

doi:10.1002/1097-0126(200102)50:2<213::aid-pi615>3.0.co;2-u

Cited by 18 publications

(2 citation statements)

References 45 publications

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“…Polyester has been used in large quantities in the textile industry and other manufactures of electronic film and tap, food packing, as well as beverage container for these decades. To achieve some special performance of polyester, copolymerization has been performed, such as poly (ethylene-co-trimethylene terephthalate) (PET-PTT) and Poly (ethylene-co-butylene terephthalate) (PET-PBT) [1][2][3] .…”

Section: Introductionmentioning

confidence: 99%

Relationship between Sequence Length and Thermal Properties of Poly(ethylene Terephthalate-Co-4, 4’-Bibenzoate) (PETBB)

Jiang

Dai

Yang

et al. 2012

AMR

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Poly(ethylene terephthalate-co-4,4’-bibenzoate)s (PETBBs) with 0-25mol% bibenzoate unit were prepared from terephthalic acid (PTA), 4,4'- bibenzoic acid (BBA) and ethylene glycol (EG). The chemical composition and number-average sequence length of the resultant PETBBs were investigated by 13C-NMR. It was improved that the chemical composition of PETBBs is identical with the feed ratio, and the number-average sequence length of PET segment (LPET) becomes reduced with increasing BBA unit. The molecular weights of PETBBs reaches the high level for practical use. DSC analysis explains that the glass transition temperature (Tg) increases almost linearly and the crystallization becomes difficulty with increasing content of BBA unit. X-ray diffraction also illustrates that both crystallinity and crystal size reduced as more BBA unit is incorporated. Moreover, the relationship between the number-average sequence length and the melting temperature was investigated. The linear correlation between the number-average sequence length (LPET) and the melting temperature was observed.

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Section: Introductionmentioning

confidence: 99%

Relationship between Sequence Length and Thermal Properties of Poly(ethylene Terephthalate-Co-4, 4’-Bibenzoate) (PETBB)

Jiang

Dai

Yang

et al. 2012

AMR

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“…Because of the similarity in the chemical structure and processing behavior of PET, PTT, poly(butylene terephthalate) (PBT), the copolymers of the three polyesters, such as poly(ethylene‐ co ‐trimethylene terephthalate) (PETT) [16–18], poly(ethylene‐ co ‐butylene terephthalate) [19, 20], and poly(trimethylene‐ co ‐butylene terephthalate) copolymers [21] have been studied enthusiastically. In our previous study [17], PETT copolymers were synthesized and the nonisothermal crystallization was investigated by DSC.…”

Section: Introductionmentioning

confidence: 99%

Thermal, rheological, mechanical, and dyeing property studies of poly(ethylene‐co‐trimethylene terephthalate) copolymer filaments

Zou

Wang

et al. 2010

Polymer Engineering & Sci

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The thermal and rheological properties of poly(ethylene‐co‐trimethylene terephthalate) (PETT) copolymer are investigated. The thermal behavior of PETT copolymers is dependent on the composition. The PETT‐15 and PETT‐85 copolymers can crystallize, whereas the PETT‐30 copolymer cannot crystallize at 5°C/min cooling rate. The copolymers have a good thermal stability, even though the addition of poly(trimethylene terephthalate) (PTT) chain causes a disadvantage to the thermal stability of the copolymers. Moreover, the PETT copolymers are a typical pseudoplastic fluid exhibiting shear thinning. With increasing the shear rate or the content of PTT units, the flow activation energy decreases and the sensitivity of the shear viscosity to the melt temperature declines. The PETT copolymer filaments have intermediate elastic recovery and dyeability between poly(ethylene terephthalate) (PET) and PTT filaments. With increasing the PTT content, the elastic recovery and dyeability of PETT copolymer filaments increase. That is to say, introducing PTT units as a minor component into the macromolecular chains is an available means to improve the properties of PET filament. The obtained PETT copolymer filaments blend the advantage of the mechanical property of PET and the elastic and dyeability of PTT filament together into one polymer and possess a softer feeling and a higher extension. POLYM. ENG. SCI., 50:1689–1695, 2010. © 2010 Society of Plastics Engineers

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Crystallization kinetics of poly(1,4-butylene-co-ethylene terephthalate)

Cited by 18 publications

References 45 publications

Relationship between Sequence Length and Thermal Properties of Poly(ethylene Terephthalate-Co-4, 4’-Bibenzoate) (PETBB)

Relationship between Sequence Length and Thermal Properties of Poly(ethylene Terephthalate-Co-4, 4’-Bibenzoate) (PETBB)

Thermal, rheological, mechanical, and dyeing property studies of poly(ethylene‐co‐trimethylene terephthalate) copolymer filaments

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