Crystallographic and (spectro)electrochemical characterizations of cobalt(II) 10-phenyl-5,15-di-p-tolylporphyrin

Dimé, Abdou K. D.; Cattey, Hélène; Lucas, Dominique; Devillers, Charles H.

doi:10.1016/j.molstruc.2020.129321

Cited by 1 publication

(1 citation statement)

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“…Electrochemistry works usually with aqueous but can use non-aqueous electrolyte solutions, with a large range of solvent having a high value of permittivity (e.g., formamide, ε = 111, µ = 3.73 D) but also with low permittivity value and a low dipole moment (e.g., 1,4-dioxane, ε = 2.3, μ = 0.45D). Except with full apolar solvent (dipolar moment close to zero, µ → 0) and very viscous solvent, it is possible to use solvent suitable for lipophilic antioxidant, using surfactant [ 66 ] or complex support electrolytes, such as tetrabutylammonium hexafluorophosphate (TBAPF6), dissolved in a mixture of organic solvents, dichloromethane and acetonitrile [ 67 ], or in acetonitrile alone [ 68 ].…”

Section: Electrochemistrymentioning

confidence: 99%

The Importance of Developing Electrochemical Sensors Based on Molecularly Imprinted Polymers for a Rapid Detection of Antioxidants

et al. 2021

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This review aims to pin out the importance of developing a technique for rapid detection of antioxidants, based on molecular imprinting techniques. It covers three major areas that have made great progress over the years in the field of research, namely: antioxidants characterization, molecular imprinting and electrochemistry, alone or combined. It also reveals the importance of bringing these three areas together for a good evaluation of antioxidants in a simple or complex medium, based on selectivity and specificity. Although numerous studies have associated antioxidants with molecular imprinting, or antioxidants with electrochemistry, but even electrochemistry with molecular imprinting to valorize different compounds, the growing prominence of antioxidants in the food, medical, and paramedical sectors deserves to combine the three areas, which may lead to innovative industrial applications with satisfactory results for both manufacturers and consumers.

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Section: Electrochemistrymentioning

confidence: 99%