2023
DOI: 10.3390/inorganics11120466
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Crystallographic Structure and Quantum-Chemical Analysis of Biologically Active Co(III)-Pyridoxal–Isothiosemicarbazone Complex

Fahad Abdulaziz,
Khulood Fahad Alabbosh,
Odeh Abdullah Odeh Alshammari
et al.

Abstract: Semicarbazones and their transition metal complexes have been investigated as biologically active compounds. This study explores the synthesis, X-ray crystallographic structure, and characterization of a novel Co(III) complex cation with a pyridoxal-isothiosemicarbazone (PLITSC) ligand, [Co(PLITSC-2H)(NH3)3]+. The structure of the complex was further elucidated by the elemental analysis and spectroscopic techniques (IR and UV–VIS). Hirshfeld surface analysis was applied for the investigation of intermolecular … Show more

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Cited by 6 publications
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“…These values nicely follow the electronegativity change of the donor atoms; further insight into these interactions is presented in the following section. The other bond lengths are within the expected range and do not change significantly upon the change in substituent, as examined previously within our research group [20][21][22][23].…”
Section: Optimization Of Structures and Comparison With Crystalograph...supporting
confidence: 80%
“…These values nicely follow the electronegativity change of the donor atoms; further insight into these interactions is presented in the following section. The other bond lengths are within the expected range and do not change significantly upon the change in substituent, as examined previously within our research group [20][21][22][23].…”
Section: Optimization Of Structures and Comparison With Crystalograph...supporting
confidence: 80%