CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2∞[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra

Liu, Haoran; Jiao, Jiahao; Tudi, Abudukadi; Liu, Qingyu; Yang, Zhihua; Pan, Shilie; Zhang, Min

doi:10.1039/d4cc01827c

Chem. Commun.

2024

DOI: 10.1039/d4cc01827c

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CsAlB₃O₆Cl: the rational construction of a KBBF-type structure with aligned ²_∞[AlB₃O₆Cl] layers via introducing unprecedented [AlO₃Cl] tetrahedra

Haoran Liu,

Jiahao Jiao,

Abudukadi Tudi

et al.

Abstract: The first aluminoborate chloride CsAlB3O6Cl containing innovative AlO3Cl tetrahedra, with the perfect planar arrangement of groups, was structurally designed and synthesized using the strategy of aluminoborate chlorination. Simultaneously, the smooth...

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Cited by 3 publications

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From β-KB₃O₄F₂ to α-KB₃O₄F₂: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

Niu,

Liu,

Gai

et al. 2024

Inorg. Chem.

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Herein, a new fluorooxoborate α-KB 3 O 4 F 2 is synthesized successfully in a closed system. It crystallizes in the P2 1 /n space group and features the rare one-dimensional (1D) zigzag [B 6 O 8 F 4 ] ∞ chains built by fundamental building blocks (FBBs) [B 6 O 9 F 4 ]. To the best of our knowledge, KB 3 O 4 F 2 is a unique example of inorganic anhydrous borate whose two polymorphs show 1D B−O/F chains constructed by different FBBs but the same symmetry operation. Different from β-KB 3 O 4 F 2 , the inconsistent arrangement of π-conjugated [B 2 O 5 ] units in α-KB 3 O 4 F 2 makes it exhibit a small birefringence (0.011@546 nm). Further, α-KB 3 O 4 F 2 owns a deep-ultraviolet (DUV) cutoff edge (<200 nm), suggesting that it has a potential application as the zero-order waveplate material in the DUV region.

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From β-KB₃O₄F₂ to α-KB₃O₄F₂: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

Niu,

Liu,

Gai

et al. 2024

Inorg. Chem.

View full text Add to dashboard Cite

show abstract

Li₃[AlP₂O₇F(OH)](H₂O)_0.5 and A[Al₂(PO₄)₂F(H₂O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

Hao,

Chen,

Hou

et al. 2024

Inorg. Chem.

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Ca₃Al₂B₈O₁₈: borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO₄] units

Yan,

Chu,

Yang

et al. 2024

Chem. Commun.

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CsAlB₃O₆Cl: the rational construction of a KBBF-type structure with aligned ²_∞[AlB₃O₆Cl] layers via introducing unprecedented [AlO₃Cl] tetrahedra

Abstract: The first aluminoborate chloride CsAlB3O6Cl containing innovative AlO3Cl tetrahedra, with the perfect planar arrangement of groups, was structurally designed and synthesized using the strategy of aluminoborate chlorination. Simultaneously, the smooth...

Cited by 3 publications

References 58 publications

From β-KB₃O₄F₂ to α-KB₃O₄F₂: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

From β-KB₃O₄F₂ to α-KB₃O₄F₂: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

Li₃[AlP₂O₇F(OH)](H₂O)_0.5 and A[Al₂(PO₄)₂F(H₂O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

Ca₃Al₂B₈O₁₈: borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO₄] units

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CsAlB3O6Cl: the rational construction of a KBBF-type structure with aligned 2∞[AlB3O6Cl] layers via introducing unprecedented [AlO3Cl] tetrahedra

Abstract: The first aluminoborate chloride CsAlB3O6Cl containing innovative AlO3Cl tetrahedra, with the perfect planar arrangement of groups, was structurally designed and synthesized using the strategy of aluminoborate chlorination. Simultaneously, the smooth...

Cited by 3 publications

References 58 publications

From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

Ca3Al2B8O18: borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO4] units

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CsAlB₃O₆Cl: the rational construction of a KBBF-type structure with aligned ²_∞[AlB₃O₆Cl] layers via introducing unprecedented [AlO₃Cl] tetrahedra

From β-KB₃O₄F₂ to α-KB₃O₄F₂: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

From β-KB₃O₄F₂ to α-KB₃O₄F₂: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

Li₃[AlP₂O₇F(OH)](H₂O)_0.5 and A[Al₂(PO₄)₂F(H₂O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

Ca₃Al₂B₈O₁₈: borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO₄] units