2021
DOI: 10.1016/j.measurement.2021.109976
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Cu(I)-based molecular emitters for quantification of fluoride and phosphate in surface waters

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Cited by 4 publications
(9 citation statements)
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“…To obtain light sources for OMS, two sets of molecular emitters were synthesized. One of them consisted of eight cyclometalated Ir(III) compounds: firstly synthesized [Ir(dfppy) 2 (bpbpy)]PF 6 (1), [Ir(ppy) 2 (bpbpy)]PF 6 (2), [Ir(pybt) 2 (bpbpy)]PF 6 (3), and synthesized according to the standard procedure: (4) [8], (5) [9], (6) [10,11], (7) [12], and (8) [13]. The second set consists of six Cu(I)-based complexes: [Cu(MePPy 3 )I] 2 [Cu 2 I 4 ] (9) [14], [Cu 4 I 4 (py) 4 ] (10) [15], [Cu(Tpdp)I] (11) [16], [CuCl(PPh 3 ) 2 (py)] (12) [17], [Cu(PPh 3 ) 3 (4-Mepy)]Br (13), and [CuI(PPh 3 ) 2 (4-Mepy)] ( 14) [18].…”
Section: Methodsmentioning
confidence: 99%
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“…To obtain light sources for OMS, two sets of molecular emitters were synthesized. One of them consisted of eight cyclometalated Ir(III) compounds: firstly synthesized [Ir(dfppy) 2 (bpbpy)]PF 6 (1), [Ir(ppy) 2 (bpbpy)]PF 6 (2), [Ir(pybt) 2 (bpbpy)]PF 6 (3), and synthesized according to the standard procedure: (4) [8], (5) [9], (6) [10,11], (7) [12], and (8) [13]. The second set consists of six Cu(I)-based complexes: [Cu(MePPy 3 )I] 2 [Cu 2 I 4 ] (9) [14], [Cu 4 I 4 (py) 4 ] (10) [15], [Cu(Tpdp)I] (11) [16], [CuCl(PPh 3 ) 2 (py)] (12) [17], [Cu(PPh 3 ) 3 (4-Mepy)]Br (13), and [CuI(PPh 3 ) 2 (4-Mepy)] ( 14) [18].…”
Section: Methodsmentioning
confidence: 99%
“…The idea is to use a combination of molecular emitters as a multichannel light source with tunable intensity and wavelength range. Cyclometalated Ir(III) complexes [6] and Cu(I)based complexes [7] were synthetized and tested in order to obtain such a light source. Each individual complex has its own emission spectrum in the visible range.…”
Section: Introductionmentioning
confidence: 99%
“…The actual emission parameters could be negligibly different from the technical specification provided by a vendor. Therefore, the flashlight used in this study had a peak maximum at 367 nm and a full width at half maximum of 14 nm (in the interval 362-376 nm) [10]. The emission peak had a Gaussian-like shape with some "tail" towards longer wavelengths.…”
Section: Oms Constructionmentioning
confidence: 99%
“…In our previous studies, we proposed a new type of light source for OMS development: luminescent complexes of various metals or molecular emitters. We showed that cyclometalated Ir(III) complexes [9] and Cu(I)-based complexes [10] could be successfully applied as a multi-band light source in the spectral range of 450-800 nm. Each luminescent complex yields a specific emission spectrum in the visible region; also, the brightness of emission bands is controllable.…”
Section: Introductionmentioning
confidence: 99%
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