Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

Cu 3(SeO4)2(SeO3OH)2(H2O)16 -The First Example of a Linear Octahedral--Tetrahedral Heptamer in InorganicCompounds. -Single crystals of the new copper selenate Cu 3(SeO4)2(SeO3OH) 2(H2O)16 are obtained by hydrothermal reaction of an aqueous solution of (UO2)NO3, Cu(NO3)2, and H2SeO4 (autoclave, 180 C, 72 h) followed by slow solvent evaporation. The compound crystallizes in the triclinin space group P1 with Z = 1. The title heptamers are formed by successive polymerization of two SeO 3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)4O2 octahedra. The octahedra and tetrahedra are linked in trans-configuration which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu 2+ . -(GURZHIY, V. V.; AL-SHURAY, A.; BRITVIN, S. N.; KRIVOVICHEV*, S. V.; Eur. J. Inorg. Chem. 2015, 32, 5311-5313, http://dx.

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ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

Gurzhiy

Al-Shuray

Britvin

et al. 2016

ChemInform

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Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

Kovrugin

Colmont

Siidra

et al. 2017

Journal of Crystal Growth

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Dehydration-driven evolution of topological complexity in ethylamonium uranyl selenates

Gurzhiy

Krivovichev

Тананаев

2017

Journal of Solid State Chemistry

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Cu₃(SeO₄)₂(SeO₃OH)₂(H₂O)₁₆ – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

Cited by 7 publications

References 31 publications

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

Dehydration-driven evolution of topological complexity in ethylamonium uranyl selenates

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Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

Cited by 7 publications

References 31 publications

ChemInform Abstract: Cu3(SeO4)2(SeO3OH)2 (H2O)16 — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

ChemInform Abstract: Cu3(SeO4)2(SeO3OH)2 (H2O)16 — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

Dehydration-driven evolution of topological complexity in ethylamonium uranyl selenates

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Product

Resources

About

Cu₃(SeO₄)₂(SeO₃OH)₂(H₂O)₁₆ – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.

ChemInform Abstract: Cu₃(SeO₄)₂(SeO₃OH)₂ (H₂O)₁₆ — The First Example of a Linear Octahedral—Tetrahedral Heptamer in Inorganic Compounds.