“…Ti is resistant to external influences and has good adhesive and gettering properties [2]. In the past two decades, Cu/Ti thin film system due to its potential applications has been studied, such as the kinetics of solid-phase interactions [3,4], microstructure [5], metallurgical [6], the formation of interface layers [7,8], thermal oxidation [9], mechanical behavior [5,6,10], and electrical properties [11]. In some Cu film systems [12][13][14][15][16][17][18], remarkable agglomeration occurs at the interfaces on annealing.…”